Polyether Polyol: Hydroxyl Value 36, Primary Hydroxyl > 65%, 60%.

Polymeric Polyol: Hydroxyl Value 28, Copolymer 20%, 40%.

Water: 3%.

80TDI and Polymeric MDI (Viscosity 300mpa): 80:20.

T12: 0.025%.

A33: 0.4%.

HR-3 Silicone Oil: 1%.

HA-1 Crosslinker: 6%.

Di(b-dimethylaminoethyl) Ether: 0.15%.

Phase One: Gas Nucleation Process

The raw materials react in the liquid phase or rely on the generation of gas substances and gas volatilization during the reaction. As the reaction progresses and a large amount of heat is generated, the amount of gas substance generated and volatilized continuously increases. When the gas concentration exceeds the saturation concentration, fine gas bubbles begin to form in the solution phase and rise. As the reaction nears its end, a milky phenomenon appears in the liquid polyurethane material, known as the "milky time."



Phase Two: Self-nucleation Process

In this stage, the gas concentration continues to increase and reaches a certain level. After that, the gas concentration gradually decreases, and new bubbles no longer form. The gas in the solution gradually reaches an equilibrium saturation concentration. During this stage, the viscosity of the liquid material gradually increases, and the gas continuously merges and expands in the gradually viscous liquid phase. The volume of the bubbles continues to expand. The viscous liquid phase forming the outer wall of the bubbles gradually thins. Due to the surface tension relationship between the gas and liquid interfaces, the bubble volume increases from small to large, gradually transforming from a spherical shape into a three-dimensional geometric shape composed of polymer thin films, finally forming an open network structure of three-dimensional micropores. In the synthesis process of polyurethane foam, this stage exhibits polymer volume expansion and foam rising.



Phase Three:

After the gas concentration drops to a certain level, bubbles no longer form. With the permeation of the gas, the concentration continues to decrease, reaching the final saturated equilibrium in the process of the polymeric foam wall transitioning from a viscous liquid state to a non-flowing solid state.

The production of block-shaped soft foam typically utilizes the batch foam machine foaming process, a gap-type production method. This method evolved from manual foaming in laboratories. The process involves immediately pouring the mixed reaction materials into an open mold resembling a wooden or metal box, hence the name "boxed foam." The molds (boxes) for boxed foam can be rectangular or cylindrical. To prevent the foam block from forming a domed top, a floating cover plate can be placed on the top of the foam during foaming. The cover plate stays closely attached to the top of the foam and gradually moves upward as the foam rises.



The main equipment for boxed foam production includes: 1) Electric-mechanical stirrer, mixing barrel; 2) Mold box; 3) Weighing tools such as scales, platform scales, measuring cups, glass syringes, and other measuring devices; 4) Stopwatch for controlling mixing time. A small amount of mold release agent is applied to the inner walls of the box to facilitate easy removal of the foam.



The advantages of producing soft foam using the boxed foam method include: low equipment investment, small footprint, simple equipment structure, easy and convenient operation and maintenance, and flexible production. Some small and underfunded domestic and township enterprises use this method to produce polyurethane soft foam. Boxed foam molding is a non-continuous production method for soft foam, so the production efficiency is lower than continuous methods, and the equipment is mostly manually operated, resulting in higher labor intensity. Production capacity is limited, and there is a greater loss in cutting foam plastics. The process parameters for boxed foam should be controlled within a certain range because even with the same formula, the foam properties may not be the same when different process parameters are used. The raw material temperature should be controlled at (25±3) degrees Celsius, mixing speed at 900 to 1000r/min, and mixing time at 5 to 12 seconds. The mixing time of the polyether and additives mixture before adding TDI can be flexibly adjusted depending on the situation, and after adding TDI, a mixing time of 3 to 5 seconds is sufficient, with the key being thorough mixing after TDI addition.



During boxed foam molding, attention should be paid to the following aspects:

1) Prepare before production, including material temperature and machine equipment inspection;

2) Measure as accurately as possible;

3) Control the mixing time appropriately;

4) Pour the mixed material liquid quickly and steadily, avoiding excessive force;

5) Ensure the box is placed steadily, with the bottom paper flat, to avoid uneven material flow during pouring;

6) When the foam rises, gently press the cover to ensure the foam rises smoothly;

7) Additives should be used as specified, and pre-mixed materials should not be left for too long.



Three types of foam equipment have emerged in boxed foam molding. Initially, various raw materials were weighed into a container according to the formula, mixed with a high-speed mixer, and poured into the box mold for foaming and shaping. This method often resulted in residue in the mixing container. An improved method used a metering pump to transport the raw materials to the mixing barrel for uniform mixing. A mechanical device automatically closed the bottom of the barrel, and compressed air was used to press the material into the foaming box for shaping. Both of these methods could create eddies due to the rapid influx of materials into the box, which might cause defects or depressions in the foam products. The most reasonable boxed foam device is to place a bottomless mixing barrel directly in the center of the foaming box. A metering pump delivers the various raw materials needed for foaming into the mixing barrel. After mixing for a few seconds, the lifting device raises the mixing barrel out of the foaming box, allowing the foaming material to flow smoothly over the entire box bottom. This prevents foam cracking due to material eddies, and ensures relatively uniform height throughout the foam.



A pressure device can be added to the expanding foam material to produce flat-topped foam, reducing waste during cutting. This device is suitable for the production of polyether-type polyurethane soft foam and high rebound soft block foam. For polyvinyl acetate polyurethane blocks, this method cannot be used due to the high viscosity of the material, and continuous methods are generally employed.

Polyurethane foam often encounters various accidents and problems during actual foaming production, each of which is caused by multiple factors. In the analysis of accidents caused by complex factors, it is generally difficult to list all influencing factors and the main factors that actually play a role. Below are 15 frequently encountered problems and their causes, let's take a look together!



1. High closed-cell content

a. Polyether polyols: high proportion of ethylene oxide, high activity, often occurs when switching to polyether polyols with different activities.

b. Process formulation: excessive tin octoate usage, high isocyanate activity, high crosslinking degree, rapid crosslinking speed, excessive amines and physical blowing agents causing low internal pressure of foam, inability to open cells when foam elasticity is high, and high TDI index can also result in high closed-cell content.



2. Shrinkage (gelation speed greater than foaming speed)

a. High closed-cell content, shrinkage during cooling.

b. Process conditions: low air temperature, low material temperature.

c. Process formulation: excessive silicone oil, excessive physical blowing agent, low TDI index.



3. Internal cracking

a. Process conditions: low air temperature, high reaction center temperature.

b. Process formulation: low TDI index, excessive tin content, high early foaming strength.

c. High activity of silicone oil, small usage.



4. Top cracking (unbalanced gasification gelation speed)

a. Process conditions: low air temperature, low material temperature.

b. Process formulation: insufficient catalyst usage, small amine usage, poor quality silicone oil.



5. Bottom corner cracking (excessive amine usage, too fast foaming speed)

Large pore surface: excessive physical blowing agent, poor quality silicone oil and catalyst.



6. Poor low-temperature performance of foam

Poor intrinsic quality of polyether polyols, same hydroxyl value, low functionality, high unsaturation, low TDI index with the same tin usage.



7. Poor air permeability

a. Weather conditions: low air temperature.

b. Raw materials: high polyether polyols, high activity silicone oil.

c. Process formulation: excessive tin or same tin usage, low water and amine content, high TDI index.



8. Poor resilience

a. Raw materials: high activity polyether polyols, low relative molecular weight, high activity silicone oil.

b. Process formulation: large amount of silicone oil, excessive tin content, more water at the same tin usage, high TDI index.



9. Poor tensile strength

a. Raw materials: excessive low molecular weight polyether polyols, low hydroxyl value functionality.

b. Process formulation: insufficient tin causes poor gelation reaction, high TDI index at the same tin usage, low crosslinking degree with less water.



10. Smoking during foaming

a. Excessive amine causes a large amount of heat to be released from the reaction of water and TDI, evaporating low boiling point substances and causing smoking.

b. If not charring, the smoke is mostly composed of TDI, low boiling point substances, and monomeric cycloalkanes in polyether polyols.



11. Foam with white streaks

Fast foaming and gelation reaction speed, slow transmission speed in continuous foaming, local compression to form a dense layer, resulting in white streaks phenomenon. The transmission speed should be increased promptly, or the material temperature should be reduced, and catalyst usage should be decreased.



12. Brittle foam

The formula has excessive water, resulting in many unreacted urea formations that are not dissolved in silicone oil, poor tin catalyst usage, insufficient crosslinking reaction, high content of low relative molecular weight polyether polyols, excessively high reaction temperature, and ether bond breakage which reduces foam strength.



13. Foam density lower than set value

Foaming index is too large due to inaccurate metering, high air temperature, low air pressure.



14. Foam with skin, edge skin, bottom voids

Excessive tin and insufficient amine, slow foaming speed, fast



15、High elongation at break

a. Raw materials: high activity polyether polyols, low functionality.

b. Process formulation: insufficient crosslinking due to low TDI index, excessive tin, and high silicone oil content.

Have you ever wondered how polyurethane plastic foam is formed? In the previous article, we revealed the basic reactions behind it: isocyanates, polyether (or polyester) polyols, and water, all work together to create this magical substance. So, does this mean that in actual production, we only need these three raw materials? The answer is far from it. In our actual production process, in order to more precisely control the reaction rate and produce products with excellent performance, we often need to harness the power of various additives. These additives not only have wide-ranging applications but also can play a huge role in making our production process more efficient and stable.



Surfactants / Silicone Oil

Surfactants, also known as silicone oil, are also called foam stabilizers. In the production process of polyurethane foam, its role is crucial. The basic duty of silicone oil is to reduce the surface tension of the foaming system, thus improving the miscibility between components, adjusting the size of bubbles, controlling the bubble structure, and enhancing foam stability. Furthermore, it also bears the responsibility of preventing foam collapse. Therefore, it can be said that silicone oil plays an indispensable role in the production of polyurethane foam.



Catalysts

Catalysts play a crucial role in the synthesis process of polyurethane, mainly by accelerating the reaction between isocyanates, water, and polyols. This reaction is a typical polymerization reaction. Without the presence of catalysts, this reaction may proceed very slowly or even not at all. Currently, catalysts on the market are mainly divided into two types: amine catalysts and organic metal catalysts. Amine catalysts are compounds based on nitrogen atoms, which can effectively promote the polymerization reaction of polyurethane. Organic metal catalysts, on the other hand, are compounds that particularly affect the reaction between polyols and isocyanates in the formation of polyurethane, usually organotin compounds. The characteristic of these catalysts lies in their ability to precisely control the reaction process, resulting in a more uniform and stable final product.



Blowing Agents

Blowing agents are substances that generate gas during the polyurethane reaction and help form foam. Depending on the way gas is generated, blowing agents are usually divided into chemical blowing agents and physical blowing agents. Chemical blowing agents refer to substances that undergo chemical changes during the reaction, generate gas, and promote foam formation. Many common substances in our daily lives are actually chemical blowing agents, such as water. Physical blowing agents, on the other hand, are substances that generate gas through physical means. For example, dichloromethane (MC) is a common physical blowing agent.



Other Additives

Relying solely on basic raw materials is far from enough to make products have outstanding performance. In order to meet various needs, other additives are cleverly incorporated into the production process, and their roles should not be underestimated. For example, flame retardants can add flame resistance to products, crosslinking agents can enhance their stability, colorants and fillers can give products a more colorful appearance and texture, and various other additives with different functions are also playing their roles. It is these carefully selected additives that comprehensively improve the performance of the products and bring users a better user experience.