What are the stages of the polyurethane foam foaming system?

Phase One: Gas Nucleation Process

The raw materials react in the liquid phase or rely on the generation of gas substances and gas volatilization during the reaction. As the reaction progresses and a large amount of heat is generated, the amount of gas substance generated and volatilized continuously increases. When the gas concentration exceeds the saturation concentration, fine gas bubbles begin to form in the solution phase and rise. As the reaction nears its end, a milky phenomenon appears in the liquid polyurethane material, known as the "milky time."

Phase Two: Self-nucleation Process

In this stage, the gas concentration continues to increase and reaches a certain level. After that, the gas concentration gradually decreases, and new bubbles no longer form. The gas in the solution gradually reaches an equilibrium saturation concentration. During this stage, the viscosity of the liquid material gradually increases, and the gas continuously merges and expands in the gradually viscous liquid phase. The volume of the bubbles continues to expand. The viscous liquid phase forming the outer wall of the bubbles gradually thins. Due to the surface tension relationship between the gas and liquid interfaces, the bubble volume increases from small to large, gradually transforming from a spherical shape into a three-dimensional geometric shape composed of polymer thin films, finally forming an open network structure of three-dimensional micropores. In the synthesis process of polyurethane foam, this stage exhibits polymer volume expansion and foam rising.

Phase Three:

After the gas concentration drops to a certain level, bubbles no longer form. With the permeation of the gas, the concentration continues to decrease, reaching the final saturated equilibrium in the process of the polymeric foam wall transitioning from a viscous liquid state to a non-flowing solid state.