The compressive resistance of a foam is related to many factors such as the structure of various chain segments composing the foam, the chemical bonds between molecules, the crystallinity of polymers, the degree of phase separation, the structure of isocyanates, and the proportion of isocyanates used.

1. Slow rebound foam is formed by the reaction of high molecular weight polyols and low molecular weight polyols with isocyanates. The soft segments formed by high molecular weight polyols have large volumes, low crosslink densities, and high activity. They are easy to compress and quickly recover after pressure is removed. The hard segments formed by low molecular weight polyols have small volumes, high crosslink densities, and low activity. They are difficult to compress and also difficult to recover after external forces are removed. This characteristic gives foams their slow rebound feature and is the basis for manufacturing slow rebound foams.

Because the properties of the soft and hard segments in slow rebound foams are different, there is a certain degree of phase separation between them. If there is no phase separation between the segments, the foam body is a tightly bound whole on a macro scale, leading to the phenomenon of "move one hair and the whole body moves," meaning it shrinks as a whole when compressed and expands when pressure is released. However, the microstructure of the foam determines that this situation cannot be achieved completely. Especially in slow rebound foams, various chain segments have different molecular structures, uneven molecular weight distributions, and unavoidable phase separation. Slight phase separation causes some hard segments, due to their low activity, to have difficulty recovering during the recovery process after external forces are removed. These "escapees" more or less restrain the recovery of soft segments, ultimately leading to shrinking.

2. The crystallinity of hard segments, which is stronger than that of soft segments, is also a reason for poor recovery. Materials have similar compatibilities, which also apply in slow rebound foams. Because the hard segments have closer cross-linking points and higher crosslink densities, the small molecules formed are more likely to aggregate together. Due to the presence of hydrogen bonds, these aggregated hydrogen-containing substances enhance the crystallinity of the material, leading to greater cohesive forces. After compression, external forces change the aggregation state of the chain segments, making it easier for polar groups to fuse together. When the external force is released, the new aggregation state, due to strong cohesive forces, is difficult to return to the pre-stressed state, resulting in shrinkage of slow rebound foams.

3. The structure of isocyanates is also a factor affecting the compression resistance of slow rebound foams. TDI is usually used to produce slow rebound foams. Because the two NCO groups in the TDI molecule are at the 2,4- and 2,6- positions, they have a certain angle between them, making them prone to deformation under stress. Especially under hot pressing conditions, significant deformation and heat loss occur, particularly evident in bra cup foams, making recovery from these deformations difficult.

4. The low NCO index of isocyanates used in the preparation of slow rebound foams is also a reason for poor recovery. The NCO index of ordinary foams is usually above 100, while in slow rebound foams , the NCO index is generally between 85-95. This means that 5-15% of the hydroxyl groups do not participate in the reaction. Therefore, although the surface of the foam appears to be a single entity, internally there is a considerable portion of chain segments that are independent of each other.

Solutions for Improving Compression Resistance of Slow Rebound Foams:

1.Use high EO polyether (so-called blowing agent polyether) to replace some slow rebound polyether.

A. High EO polyether has a low hydroxyl value and a large molecular weight. After reacting with isocyanates, the segments formed have molecular weights greater than or close to those formed when ordinary polyether reacts with isocyanates, reducing the degree of phase separation and crystallinity.

B. High EO content polyether has soft and smooth segments, which can provide good slow rebound effects. Additionally, the addition of high EO polyether can effectively improve the low-temperature resistance of slow rebound foams.

2.Add a small amount of polyether-modified polyester to increase the material's cohesive force.

The polyester segments, due to the presence of ester groups, have high internal cohesive forces and good tensile and compressive properties, significantly improving the compressive resistance of slow rebound foams.

3.Use a small amount of high-functionality and high molecular weight polyether as a crosslinking agent, and replace some ordinary polyether with high-activity polyether for slow rebound.

This disrupts the distribution of chain segments, reduces the degree of phase separation, and increases the reaction degree, reducing crystallinity.

4.Use MDI or add MDI to TDI.

MDI has a different structure from TDI and produces foams with better compression resistance and less heat loss. If using MDI, it is best to use modified MDI (with high branching and easy closure of cells); liquid MDI can also be used, as it is intramolecular cyclization and more resistant to compression. Slow rebound foams made with all MDI have much better compression resistance than pure TDI, and many manufacturers are already using this.

Polyether Polyol: Hydroxyl Value 36, Primary Hydroxyl > 65%, 60%.

Polymeric Polyol: Hydroxyl Value 28, Copolymer 20%, 40%.

Water: 3%.

80TDI and Polymeric MDI (Viscosity 300mpa): 80:20.

T12: 0.025%.

A33: 0.4%.

HR-3 Silicone Oil: 1%.

HA-1 Crosslinker: 6%.

Di(b-dimethylaminoethyl) Ether: 0.15%.

1. Core Scorching (Center temperature exceeding material's oxidation temperature)

A. Poor quality polyether polyols: excessive moisture, high peroxide content, high boiling point impurities, elevated metal ion concentration, improper use of antioxidants.

B. Formulation issues: high TDI index in low-density formulas, improper ratio of water to physical blowing agents, insufficient physical blowing agent, excessive water.

C. Climate impact: high summer temperatures, slow heat dissipation, high material temperatures, high humidity leading to center temperature surpassing oxidation temperature.

D. Improper storage: Increased TDI index leading to accumulation of heat during post-curing, resulting in elevated internal temperature and core scorching.

2. Large Compression Deformation

A. Polyether Polyol: Functionality less than 2.5, propylene oxide ratio greater than 8%, high proportion of low molecular weight components, unsaturation greater than 0.05 mol/kg.

B. Process Conditions: The reaction center temperature is too low or too high, poor post-curing, incomplete reaction, or partial scorching.

C. Process Formula: TDI index too low (controlled within 105-108), excess silicone oil stannous octoate and silicone oil, low foam air content, high closed-cell content.

3. Soft Foam (Decreased hardness at same density)

A. Polyether polyols: low functionality, low hydroxyl value, high molecular weight.

B. Process formulation: insufficient T9 octoate, slow gelation reaction, lower water content with the same amount of tin catalyst, higher amount of physical blowing agents, high dosage of highly active silicone oil, low TDI index.

4. Large Cell Size

A. Poor mixing: uneven mixing, short cream time; increase mixing head speed, reduce mixing head pressure, increase gas injection.

B. Process formulation: silicone oil below lower limit, insufficient or poor quality octoate tin, slow gelation speed.

5. Density Higher than Set Value

A. Polyether polyols: low activity, high molecular weight.

B. Process formulation: silicone oil below lower limit, low TDI index, low foam index.

C. Climate conditions: low temperature, high pressure. A 30% increase in atmospheric pressure increases density by 10-15%.

6. Collapsed Cells and Hollows (Gas evolution rate greater than gelation rate)

A. Polyether polyols: excessive acid value (affects reaction rate), high impurities, low activity, high molecular weight.

B. Process formulation: excess amine, low tin catalyst (rapid foaming and slow gelation), low TDI index, insufficient or ineffective silicone oil.

C. Low-pressure foaming machine: reduce gas injection and mixing head speed.

7. High Closed-Cell Ratio

A. Polyether polyols: high epoxy ethane ratio, high activity, often occurs when switching to polyether polyols with different activity levels.

B. Process formulation: excessive octoate tin, high isocyanate activity, high crosslinking degree, high crosslinking speed, excessive amine and physical blowing agents leading to low foam pressure, high foam elasticity resulting in poor cell opening, excessively high TDI index leading to high closed-cell ratio.

8. Shrinkage (Gelation rate greater than foaming rate)

A. High closed-cell ratio, shrinkage during cooling.

B. Process conditions: low air and material temperature.

C. Process formulation: excessive silicone oil, less amine, more tin, low TDI index.

D. Low-pressure foaming machine: increase mixing head speed, increase gas injection.

9. Cracking

A. "八" shaped cracks indicate excess amine, single line cracks indicate excess water.

B. Mid and bottom cracks: Excessive amine, fast foaming rate (excessive physical blowing agent, poor silicone oil and catalyst quality).

C. Top cracks: Unbalanced gas-evolution gelation rate (low temperature, low material temperature, insufficient catalyst, less amine, poor silicone oil quality).

D. Internal cracks: Low air temperature, high center temperature, low TDI index, excessive tin, high early foaming strength, highly active silicone oil in small quantities.

E. Side middle cracks: Increase tin dosage.

F. Cracking throughout the process may be due to discrepancies in dropping plate and foaming reaction, or premature foaming, or incorrect plates. Apart from formulation, it also relates to the smoothness of the base paper; if the base paper is wrinkled, it can divide the liquid into several parts, causing cracks.

10. Blurred Cell Structure

A. Excessive stirring speed.

B. High air injection volume.

C. Inaccurate metering pump flow.

D. Clogged material pipelines and filters.

11. Bottom Edge Cracks (Excessive amine, fast foaming rate)

Surface large pores: excessive physical blowing agent, poor silicone oil and catalyst quality.

12. Poor Low-Temperature Performance

Poor inherent quality of polyether polyols: low hydroxyl value, low functionality, high unsaturation, low TDI index with the same tin usage.

13. Poor Ventilation

A. Climate conditions: low temperature.

B. Raw materials: high polyether polyol content, highly active silicone oil.

C. Process formulation: excess tin, or low tin and amine content with the same tin usage, high TDI index.

Beginners are concerned that if the settling plate is not adjusted properly, the liquid flowing out of the nozzle may cause front surging or back surging, affecting the foaming process. Within two minutes after starting the machine, the reaction speed gradually increases, sometimes requiring adjustments to the settling plate. Adjustments to the settling plate are more critical in low-density and high-moisture-content (MC) formulas.

TDI (Toluene Diisocyanate) flow rate can be calculated to correspond to the scale value, but it is recommended to actually measure the TDI flow rate during the first foaming. Flow rate is too important; if the flow rate is not accurate, everything else will be a mess. It's best to rely on the simplest and most intuitive method of measuring the flow rate.

When mixing powders, the mixed stone powder should be left overnight and production should start the next day. For ingredients containing melamine and stone powder, it is recommended to first mix melamine with polyether for a period of time before adding the stone powder.

Foam machine formulas with long mixing chamber in the machine head or more teeth on the stirring shaft usually have less amine and lower material temperature. Conversely, foam machine formulas with short mixing chamber in the machine head or fewer teeth on the stirring shaft usually have more amine and higher material temperature.

For the same formula, when switching between dual-spray swivel heads and single-spray swivel heads with similar nozzle cross-sectional areas, the requirements for mesh thickness and layers are similar.

For the calibration of minor material flow, one method is to measure the return flow of the minor material, and the other is to calibrate it by dividing the total amount used by the foaming time. When there is a significant difference between the two calibration methods, rely on the data from the second calibration method.

Formulas for high-quality soft foam are usually within an unstable range, such as a low TDI index, low water-to-MC ratio, low T-9 dosage, and low silicone oil dosage.

How to properly control the tension of the upper thread?

When removing the thread, be sure to pass through the thread clamp on the upper thread clamp. The thread clamp cannot be adjusted too tight. When you need to adjust the tightness of the upper thread, you cannot pull the upper thread directly. You must control the tightness of the upper thread through the thread clamp on the control device; when adjusting, it should not be too tight or too loose, and there should be no jamming, otherwise it will cause jumpers. Or disconnected.

How to draw a pattern?

When drawing a pattern for a quilting machine, we can use professional pattern drawing software, but the exported format must be HFP. How to enlarge or reduce the size when drawing a floral pattern? In "Edit Pattern", open "Scale Entire Pattern", and based on our needs, click on the pop-up box's "millimeters" or "inches" option, then add the X and Y parameters according to our needs, and click "OK" after entering.

How to troubleshoot the cause of abnormal noise in a quilting machine?

First, check whether the frequently worn parts are lacking oil, and add some machine oil or grease to the dryer areas; then check whether there is any clearance in the bearings of various components; also carefully observe whether the accessories and wear parts are excessively worn, and replace them timely if discovered.