In September 2021, we received an inquiry from Mr. Abdullah in Saudi Arabia regarding a continuous foaming machine. The client was planning to establish a PU foam factory to produce products for the local and Yemeni markets. He had some basic knowledge about machine usage and selection.



The client had no prior experience in foam production before, so he was particularly concerned about after-sales support and technical assistance.



We began by analyzing the client's target market (specific industry) and understanding the local product requirements (such as foam density, hardness, etc.) to confirm the client's production needs.



Through video conferences, we guided the client through our PU foam production process, providing the client with a concrete understanding of foam production and highlighting the convenience and efficiency advantages of our machines compared to those of other manufacturers.



Drawing upon our more than 20 years of experience in foam foaming, we shared insights with the client about using the machine and common challenges in the foam foaming process, addressing any technical concerns the client may have had.



We also provided the client with factory layout plans to expedite the setup of the entire foam production line while maximizing production efficiency.

Due to the client's high level of trust in our professional service, he ultimately chose us as his supplier for foam machinery and later made repeat purchases for a rebonded foam production line and foam cutting machines.

Aluminum Hydroxide

Also known as hydrated alumina. The aluminum hydroxide used as a fire retardant is mainly @-tri-hydrated alumina. It appears as a white fine crystalline powder with an average particle size of 1-20 micrometers. Its relative density is 2.42, refractive index is 1.57, and 30% slurry pH is 9.5-10.5. The dehydration initiation temperature is 200 degrees Celsius, with an absorption heat of 2.0 KJ/G.

During combustion, it releases a large amount of chemically combined water, absorbs a considerable amount of heat, slows down the polymer's thermal degradation rate, reduces the material surface temperature, delays and suppresses the combustion of the substrate. It will generate a large amount of steam on the substrate surface, diluting the oxygen in the combustion zone, reducing the concentration of smoke and toxic flammable gases. The aluminum oxide generated during combustion can promote the formation of a carbonized protective layer on the polymer surface.



Melamine

Commonly known as melamine, it is a white monoclinic crystal with low toxicity, non-flammable, and a melting point of 354 degrees Celsius. It undergoes endothermic sublimation and rapid decomposition under high heat. At temperatures between 250-450 degrees Celsius, it can absorb a large amount of heat and release nitrogen during decomposition, slowing down the material's combustion rate. At the same time, it forms a carbonized barrier layer on the substrate surface, acting as a fire retardant. However, there are some dispersion problems, so it needs to be used in combination. When used as a fire retardant, high-temperature decomposition can produce toxic cyanide gas.



Organophosphorus Flame Retardant

Tris(1,3-dichloro-2-propyl)phosphate (TDCPP)

A pale yellow transparent viscous liquid. It contains 7.2% phosphorus and 49.4% chlorine, with a flash point of 251.7 degrees Celsius, ignition point of 282 degrees Celsius, and spontaneous combustion temperature of 514 degrees Celsius. It starts to decompose at 230 degrees Celsius and is soluble in alcohols, benzene, carbon tetrachloride, etc. When used at 5%, it can achieve self-extinguishing properties, and at 10%, it can make the material self-extinguish or non-flammable, while also having water resistance, light resistance, and antistatic properties.



Fire Retardant Polyether Polyol

1. Formula Ingredients:

Polyether polyol 3050: Mn3000;

Flame-retardant polyether polyol: Hydroxyl value 28, flame-retardant solid mass fraction 23%;

Silicone oil: L580

Triethylene diamine solution: Mass fraction 33%;

Tin octoate solution: Mass fraction 33%;

TDI: Industrial grade

Beginners are concerned that if the settling plate is not adjusted properly, the liquid flowing out of the nozzle may cause front surging or back surging, affecting the foaming process. Within two minutes after starting the machine, the reaction speed gradually increases, sometimes requiring adjustments to the settling plate. Adjustments to the settling plate are more critical in low-density and high-moisture-content (MC) formulas.



TDI (Toluene Diisocyanate) flow rate can be calculated to correspond to the scale value, but it is recommended to actually measure the TDI flow rate during the first foaming. Flow rate is too important; if the flow rate is not accurate, everything else will be a mess. It's best to rely on the simplest and most intuitive method of measuring the flow rate.



When mixing powders, the mixed stone powder should be left overnight and production should start the next day. For ingredients containing melamine and stone powder, it is recommended to first mix melamine with polyether for a period of time before adding the stone powder.



Foam machine formulas with long mixing chamber in the machine head or more teeth on the stirring shaft usually have less amine and lower material temperature. Conversely, foam machine formulas with short mixing chamber in the machine head or fewer teeth on the stirring shaft usually have more amine and higher material temperature.



For the same formula, when switching between dual-spray swivel heads and single-spray swivel heads with similar nozzle cross-sectional areas, the requirements for mesh thickness and layers are similar.



For the calibration of minor material flow, one method is to measure the return flow of the minor material, and the other is to calibrate it by dividing the total amount used by the foaming time. When there is a significant difference between the two calibration methods, rely on the data from the second calibration method.



Formulas for high-quality soft foam are usually within an unstable range, such as a low TDI index, low water-to-MC ratio, low T-9 dosage, and low silicone oil dosage.

The production of block-shaped soft foam typically utilizes the batch foam machine foaming process, a gap-type production method. This method evolved from manual foaming in laboratories. The process involves immediately pouring the mixed reaction materials into an open mold resembling a wooden or metal box, hence the name "boxed foam." The molds (boxes) for boxed foam can be rectangular or cylindrical. To prevent the foam block from forming a domed top, a floating cover plate can be placed on the top of the foam during foaming. The cover plate stays closely attached to the top of the foam and gradually moves upward as the foam rises.



The main equipment for boxed foam production includes: 1) Electric-mechanical stirrer, mixing barrel; 2) Mold box; 3) Weighing tools such as scales, platform scales, measuring cups, glass syringes, and other measuring devices; 4) Stopwatch for controlling mixing time. A small amount of mold release agent is applied to the inner walls of the box to facilitate easy removal of the foam.



The advantages of producing soft foam using the boxed foam method include: low equipment investment, small footprint, simple equipment structure, easy and convenient operation and maintenance, and flexible production. Some small and underfunded domestic and township enterprises use this method to produce polyurethane soft foam. Boxed foam molding is a non-continuous production method for soft foam, so the production efficiency is lower than continuous methods, and the equipment is mostly manually operated, resulting in higher labor intensity. Production capacity is limited, and there is a greater loss in cutting foam plastics. The process parameters for boxed foam should be controlled within a certain range because even with the same formula, the foam properties may not be the same when different process parameters are used. The raw material temperature should be controlled at (25±3) degrees Celsius, mixing speed at 900 to 1000r/min, and mixing time at 5 to 12 seconds. The mixing time of the polyether and additives mixture before adding TDI can be flexibly adjusted depending on the situation, and after adding TDI, a mixing time of 3 to 5 seconds is sufficient, with the key being thorough mixing after TDI addition.



During boxed foam molding, attention should be paid to the following aspects:

1) Prepare before production, including material temperature and machine equipment inspection;

2) Measure as accurately as possible;

3) Control the mixing time appropriately;

4) Pour the mixed material liquid quickly and steadily, avoiding excessive force;

5) Ensure the box is placed steadily, with the bottom paper flat, to avoid uneven material flow during pouring;

6) When the foam rises, gently press the cover to ensure the foam rises smoothly;

7) Additives should be used as specified, and pre-mixed materials should not be left for too long.



Three types of foam equipment have emerged in boxed foam molding. Initially, various raw materials were weighed into a container according to the formula, mixed with a high-speed mixer, and poured into the box mold for foaming and shaping. This method often resulted in residue in the mixing container. An improved method used a metering pump to transport the raw materials to the mixing barrel for uniform mixing. A mechanical device automatically closed the bottom of the barrel, and compressed air was used to press the material into the foaming box for shaping. Both of these methods could create eddies due to the rapid influx of materials into the box, which might cause defects or depressions in the foam products. The most reasonable boxed foam device is to place a bottomless mixing barrel directly in the center of the foaming box. A metering pump delivers the various raw materials needed for foaming into the mixing barrel. After mixing for a few seconds, the lifting device raises the mixing barrel out of the foaming box, allowing the foaming material to flow smoothly over the entire box bottom. This prevents foam cracking due to material eddies, and ensures relatively uniform height throughout the foam.



A pressure device can be added to the expanding foam material to produce flat-topped foam, reducing waste during cutting. This device is suitable for the production of polyether-type polyurethane soft foam and high rebound soft block foam. For polyvinyl acetate polyurethane blocks, this method cannot be used due to the high viscosity of the material, and continuous methods are generally employed.

What is Polyurethane Rigid Foam?



Polyurethane rigid foam, often abbreviated as PU rigid foam, is one of the most commonly used polyurethane products, second only to polyurethane soft foam, in polyurethane applications. Polyurethane rigid foam is mostly a closed-cell structure, known for its excellent insulation, lightweight, high strength-to-weight ratio, ease of construction, as well as soundproofing, shock absorption, electrical insulation, heat resistance, cold resistance, solvent resistance, and more. It is widely used in the insulation layers of refrigerator and freezer boxes, cold storage rooms, refrigerated trucks, as well as insulation materials for buildings, tanks, and pipelines. A small amount is used in non-insulation applications such as wood imitation and packaging materials. Generally, lower-density polyurethane rigid foam is primarily used as thermal insulation material, while higher-density polyurethane rigid foam can be used as structural material (wood imitation).



Polyurethane rigid foam is typically foamed at room temperature, with a relatively simple molding process. It can be categorized into manual foaming and mechanical foaming based on the degree of construction mechanization; high-pressure foaming and low-pressure foaming based on the foaming pressure; and casting foaming and spraying foaming based on the molding method.



What is Polyurethane Soft Foam?



Polyurethane soft foam, also known as PU soft foam, is a type of flexible polyurethane foam with a certain degree of elasticity. It is the most extensively used polyurethane product among all polyurethane products.



Polyurethane soft foam is mostly an open-cell structure, characterized by low density, good elastic recovery, sound absorption, breathability, and insulation properties. It is primarily used as cushioning materials for furniture, mattresses, vehicle seat cushions, and also finds industrial and domestic applications as filter materials, soundproofing materials, shock absorption materials, decorative materials, packaging materials, and insulation materials. Based on the degree of softness and load-bearing capacity, polyurethane soft foam can be divided into ordinary soft foam, super soft foam, high load-bearing soft foam, high resilience soft foam, etc. High resilience and high load-bearing soft foams are generally used for manufacturing seat cushions and mattresses. According to the production process, polyurethane soft foam can be divided into block foam and molded foam. Block foam is produced by continuous process to form large volume foam which is then cut into required shapes, while molded foam is produced by direct injection of the mixture into molds to form foam products of desired shapes.



After understanding polyurethane rigid foam and polyurethane soft foam, the question arises: how do we differentiate between the two?



In fact, the classification can be based on the degree of hardness, dividing them into soft foam plastics and hard plastics. Soft foam plastics have a matrix polymer component above the crystalline melting point, or, if it is an amorphous polymer, it is above the glass transition temperature; hard foam, on the other hand, has its matrix polymer in a crystalline state or an amorphous state but below the glass transition temperature. Semi-rigid foam is a foam plastic between soft and hard foam. It is similar to soft foam, with an open cell rate above 90℃, but semi-rigid foam has higher density and higher compression strength. After compression deformation, semi-rigid foam takes much longer to recover, and its crosslinking density is much higher than soft foam but lower than hard foam.



Based on this classification of softness and hardness, most polyolefin foams, unplasticized polyvinyl chloride (PVC) foams, phenolic foams, polycarbonate foams, and polyphenylene ether foams are all classified as hard foams, while elastic polyurethane foams and some polyolefin foams and plasticized PVC foams are classified as soft foams.



According to the national standard, soft foam plastics are those that are flexible, have low compression hardness, return to their original state after stress is relieved, and have minimal residual deformation. On the other hand, hard foam plastics are inflexible, have high compression hardness, deform when stress reaches a certain level, and do not return to their original state after stress is relieved.



The American Society for Testing and Materials (ASTM) specifies that to differentiate between soft and hard foam plastics, at a temperature of 18-29℃, a rod with a diameter of 2.5 cm is rotated around it for one full rotation within 5 seconds. If it does not fracture, it is classified as soft foam plastic; otherwise, it is classified as hard foam plastic.



According to ISO standards, when the compression deformation reaches 50% and is then released, if the thickness decreases by no more than 2% compared to the original thickness, it is classified as soft foam plastic. If it decreases by more than 10%, it is classified as hard foam plastic. If the decrease is between 2-10%, it is classified as semi-rigid foam plastic.



If we use elastic modulus as the criterion, in a standard environment of 23℃ and 50% relative humidity, a foam plastic with an elastic modulus greater than 686 MPa is classified as hard foam, less than 68.6 MPa is classified as soft foam, and between 68.6-686 MPa is classified as semi-rigid foam. Although the elastic modulus of semi-rigid foam is higher than that of soft foam, its stress-strain behavior is closer to soft foam and significantly different from hard foam. Generally, soft foam plastics mostly have an open-cell structure, while hard foam plastics mostly have a closed-cell structure, but there are exceptions.