For many small-scale enterprises, although the continuous production line of polyurethane flexible foam offers high output, the costs are also very high, and the target market may not require such large quantities. As a result, non-continuous production lines for polyurethane flexible foam have become their preferable choice. The following is an introduction to the non-continuous production line for polyurethane flexible foam:

1. Box Foaming Process Equipment

The box foaming process and equipment have been developed as a new technology to accommodate the needs of small-scale polyurethane foam production facilities. It builds upon laboratory and manual foam production techniques, essentially an upscaled version of laboratory foam methods. This process has gone through three development stages. Initially, all component materials were sequentially weighed and added to a larger container, followed by the addition of TDI. After rapid mixing, the mixture was immediately poured into a large box mold. This method had high labor intensity, emitted high concentrations of toxic gases, and posed significant health risks to operators. Additionally, the splattering of materials during pouring would entrain a large amount of air, leading to the formation of large air bubbles within the foam structure and even causing foam cracking. Furthermore, there was a significant amount of leftover waste, resulting in substantial material waste and high production costs.

Later on, the process incorporated metering pumps to convey materials to a mixing barrel with an automatically opening bottom. After high-speed mixing, the bottom plate of the mixing barrel would open, and compressed air would swiftly expel the material into the mold for foam expansion. However, this approach suffered from uneven foam pore structures due to the rapid material flow, leading to swirling foam structures and quality issues like crescent-shaped cracks. The third stage of process improvement is the box foaming device that is mostly adopted today. Its fundamental foaming principle is illustrated in Picture



(a) Raw Material Metering and Mixing (b) Foaming (c) Foam Rises to Limit Height

1 - Elevatable Material Mixing Barrel; 2 - Assemblable Box Mold; 3 - Floating Box Top Plate; 4 - Foam Body

Picture 1: Schematic Diagram of Box Foaming Principle

The industrial production equipment for box foaming primarily consists of raw material tanks, metering pump units, elevatable mixing barrels, and assemblable wooden box molds. As depicted in the schematic diagram of the box foaming equipment manufactured by Hennecke (Picture 2), the foaming raw materials are stored in tanks and regulated by control devices to attain the required processing temperature range, typically maintained at 23°C ± 3°C. Sequentially, the metering pump injects polyether polyols, catalyst, surfactants, foaming agents, etc., into the mixing barrel for a stirring duration of 30 to 60 minutes. Next, according to the formulation, TDI is introduced, either directly or through an intermediate container with a bottom switch. Immediate mixing follows TDI addition. Depending on the materials and formulation, the stirring speed is usually controlled at 900 to 1000 revolutions per minute (r/min), with a stirring time of 3 to 8 seconds. After stirring, the mixing barrel is swiftly lifted. The lower part of the barrel lacks a bottom and is placed on the mold box's bottom plate upon lowering, utilizing a sealing ring at the barrel's bottom edge to prevent material leakage.

When lifted, the well-mixed slurry can be directly spread and dispersed on the bottom plate of the box mold, allowing natural foam rise. To prevent the formation of a domed surface on the upper part during foaming, an upper mold plate that matches the mold area and allows for upward limit movement is equipped. The mold box primarily comprises rigid wooden panels, with the bottom plate fixed on a movable mold transport carriage. All four side panels are assemblable, featuring quick-opening and closing locking mechanisms. The inner sides of the panels are coated with silicone-based release agents or lined with polyethylene film material to prevent adhesion. After 8 to 10 minutes of forced maturation within the box, the side panels of the mold box are opened, allowing the removal of block-shaped flexible foam. Following an additional 24 hours of maturation, these foam blocks can undergo cutting and other post-processing procedures.





1 - Raw Material Tank; 2 - Metering Pump Unit; 3 - Control Cabinet; 4 - Mixing Barrel with Elevating Device; 5 - Foaming Box; 6 - Foam Finished Product; 7 - Floating Plate

Picture 2: Box Foaming Equipment Manufactured by Hennecke (BFM100/BFM150)

Box foaming process and equipment exhibit characteristics such as simple operation, compact and straightforward equipment structure, low investment, small footprint, and convenient maintenance. These features make it particularly suitable for small enterprises engaged in intermittent production of low-density block foam. However, its drawbacks are also quite evident: lower production efficiency, less favorable production environment, high concentration of emitted toxic gases on-site, necessitating the use of highly effective exhaust and toxic gas purification systems.



To enhance mixing efficiency, some companies have added several vertical and equidistant baffles to the inner walls of the mixing barrel. These baffles, combined with high-speed spiral-type agitators, facilitate high-speed mixing. This approach can to a certain extent reduce laminar flow effects in the mixing liquid and improve mixing efficiency. An example of this is our product, the SAB-BF3302. For the product's appearance and technical specifications, please refer to Picture 3.



Picture 3: Fully Automatic Box Foaming Machine (Sabtech Technology Limited)

This production line comes with both fully automatic computer control and manual control modes. It's suitable for producing flexible polyurethane foam with densities ranging from 10 to 60 kg/cm. Maximum foam output: 180L. Foam height: 1200mm. Mixing power: 7.5kW. Total power: 35kW.

2. Equipment for Open-Cell Foam Preparation

Open-cell polyurethane foam is a functional foam product developed in the 1980s. It possesses a high porosity, a distinct network structure, softness, breathability, and good mechanical strength. It finds wide application as excellent filtration and shock-absorption material in transportation, instrumentation, medical material filtration membranes, and as catalyst carriers in the chemical industry. Filling it into aircraft fuel tanks can suppress oil agitation and reduce the risk of explosions. Impregnating it with ceramic slurry and high-temperature sintering results in a novel open-cell ceramic filter material used in the metallurgical industry.

The preparation of open-cell polyurethane foam involves methods such as steam hydrolysis, alkaline soaking, and explosion. In industrial production, the explosion method is predominantly used. Initially, polyurethane foam of a specific pore size is prepared using the box foaming process. Subsequently, it's placed in dedicated explosion network equipment, filled with explosive gas, and ignited after completely filling the foam body. By utilizing the impact energy and high-temperature heat generated by the explosion parameters, the cell walls of the polyurethane foam are ruptured and fused onto the cell walls, forming a distinct network structure, as shown in Picture 4.



Picture 4: Clearly Networked Open-Cell Foam

Methods like steam hydrolysis or alkaline soaking are used to prepare open-cell foam. However, there are issues of low efficiency, poor quality, and environmental pollution with these methods. They are mainly employed for small-scale production such as laboratory sample testing. Large-scale production primarily uses the explosion method.



ATL Schubs GmbH, a German company, specializes in the research and development of polyurethane reticulated foam and manufactures the ReticulatusTM foam explosion machinery. The explosion chamber of the reticulated foam explosion equipment comes in two forms: cylindrical and rectangular. The former is suitable for cylindrical foam, while the latter is more versatile. It can be used not only for square foam but also for processing reticulated foam from cylindrical foam, as shown in Picture 5. The explosion chamber is constructed from high-quality 100mm-thick steel plates. Operation is controlled by a computer modem, offering features like automatic opening and closing, automatic locking, automatic operation, and automatic alerts. Additionally, remote program design and modification can be facilitated through data transmission sensors.



Picture 5: Polyurethane Foam Reticulation Processing Equipment (ATL Schubs)

During production, foam bodies measuring 3 to 6 meters in length that are intended for reticulation are pushed into the explosion chamber. The chamber's door is closed hydraulically, and the air inside the chamber is evacuated using a vacuum pump. Under computer control, a precise proportion of oxygen and hydrogen gases is introduced, and the gas mixture's ratio is mechanically adjusted based on factors such as foam sample type and network size requirements.

Sensors continuously monitor the process, ensuring that all process parameters are within the specified conditions before controlled detonation is initiated. The explosive force and flame intensity generated by the explosion penetrate through the entire foam body, creating a distinct network structure. After forming, the foam body is cooled, residual materials and waste gases are purged using nitrogen, and the pressure chamber can then be opened to retrieve the reticulated foam. The entire process takes approximately 8 to 10 minutes. The pore diameter of the reticulated foam falls within the range of 10 to 100 pores per inch (ppi) (Note: ppi refers to the number of pores within one inch).

The above provides some insight into the non-continuous production process of polyurethane flexible foam. I hope this information proves helpful to you.

When using a batch foam machine for polyurethane soft foam foaming, have you encountered the following situations?

1.Uneven and numerous foam pores,

2. Rough foam texture.

3. Chaotic pore sizes across the entire foam surface, with slight signs of large pores.

Issues like these are quite common. The main reason for the first issue is that the distance between the mixing impeller of the foam machine and the bottom of the mixing barrel is too great; the second issue is that the mixing blades are too short and narrow: the third issue is that the angle of the mixing blades is too large.

Many manufacturers who design and produce foam machines only understand the principles during the design process, without understanding the significant relationship between a different design in foam production and product quality. A reasonable and perfect mechanical design can only be gradually improved in actual work, and only experienced foamers can achieve this.

Here are some experiences we have had with machine modifications and upgrades, hoping they will be helpful:

First, the installation position of the mixing wheel should be as low as possible, closer to the bottom of the mixing barrel is better. In general, the distance between the lowest point of the mixing blade and the bottom of the mixing barrel should be around two centimeters

Second, the shape of the mixing blade should be fan-shaped, with a moderately wide edge. The advantage of being wide is that it increases the contact area with the liquid material, providing sufficient power and also balances the liquid material.

Third, the length of the mixing blade should also be as long as possible, leaving about three to four centimeters from the baffle inside the mixing barrel.

Fourth, the two edges of the mixing blade should be sloped, with the angle of inclination based on the width of one end and two centimeters difference on both sides. After the mixing blade is modified, proper operation is also crucial, especially the mixing speed. Most batch foam machines nowadays are equipped with high-speed timing frequency conversion devices. However, in actual production, this device is often unnecessary. The operating speed mainly depends on the amount of material in the mixing barrel. If there is a lot of material, the speed should be appropriately faster, and if there is less material, then the speed should be lower.

Manufacturing polyurethane filter foam typically involves two key stages. The first stage involves preparing open-cell or partially open-cell polyurethane foam according to the desired porosity. If the foam is closed-cell, it needs to be subjected to roller compression to rupture the cell walls, thereby creating the necessary porous structure. The second stage is to remove all the cell membranes to form a reticulated structure.



To produce polyurethane filter foam, the size of the pores and the structure of the network of the foam are largely determined by the catalyst, foaming agent, and surfactant.



In practical operations, there are two common methods for forming the network:



First is the alkali hydrolysis method. The steps of this method involve immersing the soft polyester-type polyurethane foam obtained from the first stage in a 10% sodium hydroxide solution at 50 degrees Celsius for about 10 minutes. Then it goes through processes such as washing with water, neutralization with acetic acid, another round of water washing, and drying, resulting in the final product of polyurethane filter foam.



Another method is the combustion method, also known as the explosion method. This method requires placing the soft polyether-type or polyester-type polyurethane foam obtained from the first stage into a sealed container. The container is then evacuated to 13.3 Pa, followed by the introduction of oxygen and natural gas (in a volumetric ratio of 2:1), bringing the internal pressure of the container to a certain level (which increases with the porosity). Next, the gas inside the container is ignited using a spark plug. The heat generated from the combustion process will burn off or melt the cell membranes without damaging the cell struts. Finally, the resulting product after combustion is cleared with air, and the filter foam is removed from the container.



Both of these methods are effective ways to prepare polyurethane filter foam, and the specific choice between them depends on the material of the foam and the desired structural characteristics.

Beginners are concerned that if the settling plate is not adjusted properly, the liquid flowing out of the nozzle may cause front surging or back surging, affecting the foaming process. Within two minutes after starting the machine, the reaction speed gradually increases, sometimes requiring adjustments to the settling plate. Adjustments to the settling plate are more critical in low-density and high-moisture-content (MC) formulas.



TDI (Toluene Diisocyanate) flow rate can be calculated to correspond to the scale value, but it is recommended to actually measure the TDI flow rate during the first foaming. Flow rate is too important; if the flow rate is not accurate, everything else will be a mess. It's best to rely on the simplest and most intuitive method of measuring the flow rate.



When mixing powders, the mixed stone powder should be left overnight and production should start the next day. For ingredients containing melamine and stone powder, it is recommended to first mix melamine with polyether for a period of time before adding the stone powder.



Foam machine formulas with long mixing chamber in the machine head or more teeth on the stirring shaft usually have less amine and lower material temperature. Conversely, foam machine formulas with short mixing chamber in the machine head or fewer teeth on the stirring shaft usually have more amine and higher material temperature.



For the same formula, when switching between dual-spray swivel heads and single-spray swivel heads with similar nozzle cross-sectional areas, the requirements for mesh thickness and layers are similar.



For the calibration of minor material flow, one method is to measure the return flow of the minor material, and the other is to calibrate it by dividing the total amount used by the foaming time. When there is a significant difference between the two calibration methods, rely on the data from the second calibration method.



Formulas for high-quality soft foam are usually within an unstable range, such as a low TDI index, low water-to-MC ratio, low T-9 dosage, and low silicone oil dosage.

Calculation of foaming distance for continuous foaming machine



Given: Bubble release time for the formula is 108 seconds, conveyor belt speed during foaming is 4.6 meters per minute. Calculate the swinging and trough foaming distances.

Foaming distance when swinging: (108/60) x 4.6 = 8.28 meters

Foaming distance when troughing: [((108-18)/60)] x 4.6 = 6.9 meters



Explanation: For the same formula, continuous foaming machine has a shorter bubble release time than small bubbles. The calculated foaming distance is shorter than the actual foaming distance. This method only provides approximate confirmation of the foaming distance, supporting the adjustment of the settling plate. Troughing: 18" indicates the time in seconds that the raw material stays in the overflow trough.



Calculation of foaming height for continuous foaming machine



Given: Formula flow rate: 80 kilograms per minute for polyether, 20 for white polyether, 60 for TDI, 20 for stone powder, conveyor belt speed 4.5 meters per minute, mold width 1.65 meters, producing foam with a density of 25 kilograms per cubic meter. What is the foaming height in meters?

Total formula weight: 80 + 20 + 60 + 20 = 180 kilograms

Formula volume: 180/25 = 7.2 cubic meters

Base area of conveyor running per minute:

4.5 x 1.65 = 7.425 cubic meters

Foaming height: 7.2/7.425 = 0.97 meters



Explanation: Silicone oil, amine, and tin are not considered here as they offset the amount of carbon dioxide used during the foaming process. Moisture content (MC) is not considered because MC does not increase foam weight when vaporized.



Foaming Daily Operation

Beginners worry that improper adjustment of the settling plate will cause the liquid sprayed from the nozzle to surge forward or backward, affecting foaming. The reaction rate gradually increases within the first two minutes after starting the machine, sometimes requiring corresponding adjustments to the settling plate. Adjustments to the settling plate are more critical in formulas with low density and high MC.

TDI flow rate can be calculated by determining the corresponding scale value for the flow rate, but it is recommended to measure the TDI flow rate during the first foam production. Flow rate is too important; if the flow rate is incorrect, everything else will be a mess. It's best to rely on the simplest and most intuitive method of measuring flow rate.

When powder is being mixed, the mixed stone powder should be left overnight and production should start the next day. For formulations containing melamine and stone powder, it is recommended to first mix the melamine with the polyether for a period of time before adding the stone powder.

Formulas for foam machines with longer mixing chamber or more teeth on the mixing shaft typically have less amine and lower material temperature. Conversely, formulas for foam machines with shorter mixing chamber or fewer teeth on the mixing shaft typically have more amine and higher material temperature.

For the same formula, when switching between dual spray swing heads and single spray swing heads, if the cross-sectional area of the two nozzles is similar, the requirements for the fineness and number of layers of the mesh are similar.

Correction of small material flow rate can be done by measuring the return flow rate of the small material, or by dividing the total usage by the foaming time for correction. When the values obtained from the two correction methods differ significantly, the data from the second correction method should be used.

Formulas for soft foam with better properties are usually in an unstable range, such as lower TDI index, lower water to MC ratio, lower T-9 dosage, and lower silicone oil dosage. Just like in our jobs, there must be effort before reward.