Polyurethane material is a block polymer containing carbamate characteristic groups produced by the reaction of polyisocyanate and hydrogen donor. Because of the various appearance forms of the generated products, its application has entered various fields of the world economy. The following is an overview of the horizontal continuous production line for polyurethane flexible block foam.

1. Hennecke flat top method

The continuous production line equipment for large-scale flexible polyurethane foam blocks was designed and put into production by Hennecke Company in Germany in 1952, which is the basis for continuous production of polyurethane foam blocks. Many companies have successively designed and manufactured continuous production lines for various forms of block bubbles, but only the basic principles designed by Hennecke have been used to this day. The production equipment is shown in Picture 1.

Pic 1 Schematic diagram of Hennecke polyurethane soft foam flat top continuous foaming production line

The polyurethane flexible foam continuous production line produced by Hennecke consists of several main parts: raw material supply section, mixing and pouring section, foaming and curing section, cutting section, post-curing section, and post-processing of the product. This production line has high production efficiency and requires a large supply of raw materials. Therefore, in addition to equipping tanks for polyols and isocyanates, separate systems for raw material storage, process parameters, condition control, and preparation are necessary to ensure a continuous supply of prepared raw materials to the production line during continuous operation (Picture 2).

Pic 2: Metering supply systems and mixing head input systems for 22 components

Temperature has a significant impact on the foaming reaction, and strict control of raw material temperature is necessary during foaming. Typically, the temperature is controlled within the range of 18 to 25°C, with a temperature fluctuation range of around 1°C. High-precision metering pumps are used for the metering and delivery of raw material components, with a general viscosity range of less than 2000 mPas. For high viscosity components such as colorants and flame retardants, gear pumps can be used. To prevent leakage of isocyanate components, the use of magnetic couplings is recommended. For convenience of operation and improved metering accuracy, some additives are now combined to reduce the number of metering pumps. However, it's important to note that certain additives, such as organic tin catalysts, are sensitive to other components and prone to degradation.

The mixing device used in this production line typically employs a low-pressure mixing head, with the agitator driven by a variable-speed motor at a rotational speed of 3000 to 6000 r/min. In modern continuous block foam production enterprises, high-pressure metering, mixing, and foaming equipment have also been adopted, allowing for adjustments in the mixing head's stirring form, flow rate, and nozzle size to enhance product quality. An air input device can also be configured at the mixing head to create gas nuclei and generate a fine and dense cell structure.

Well-mixed material is continuously discharged from the mixing head under certain pressure. To prevent material splashing and the entrapment of a large amount of air causing large voids within the foam body, various measures are taken during the foaming process. Apart from reducing the distance between the mixing head and the bottom plate and minimizing impact force, special designed baffles, horn-shaped or duckbill-shaped deflection tubes, and metal meshes are installed in the front part of the mixing head's outlet to reduce the impact energy of the material. 

Meanwhile, the distance from the material outlet pipe to the bottom plate needs to be decreased to around 10 mm. To ensure the uniformly distributed material on the bottom plate, cross beams are set up on the production line. The mixing head can be adjusted to move left and right in coordination with the bottom plate conveyor belt's movement speed. Alternatively, the material can be divided into multiple conduits to enter distribution slots arranged laterally in the direction of the bottom plate's movement, ensuring the material is evenly distributed on the conveyor belt, as shown in Picture 3.

Pic 3 In order to prevent the spit out material from splashing, the mixing head is equipped with some deflectors

The material ejected from the mixing head exhibits good flowability before the emulsification time. As the reaction progresses, the mixed material gradually initiates and expands. At the front end of the conveyor belt in the ejection section, the conveyor belt should be inclined at an angle of 3° to 9° and equipped with hydraulic or manual adjustment devices. This allows for appropriate adjustments of the incline angle according to process requirements, ensuring the material flows and initiates uniformly in one direction. If the incline angle is too small or the conveyor belt's movement speed is too slow, the foam thickness increases, and initiating the foam becomes difficult. If the incline angle is too large, the ejected material will flow too quickly, reaching the lower part of the foam layer that has already started to rise, causing cracks in the foam body.

Typically, for high-flow-rate units, the conveyor belt's movement speed is controlled at 3 to 10 m/min, while for medium-sized units, it's controlled at 1.5 to 3 m/min. During operation, it's crucial to carefully adjust process parameters such as the ejection rate, conveyor belt angle, and movement speed to maintain a suitable distance of 300 to 600 mm between the ejected distribution line and the milky line formed during foam initiation.

The mixed material ejected from the mixing head is directly distributed onto the pre-laid liner paper on the conveyor belt. In the foaming section, a conveying and recovery device is assembled, including conveyor belts, a drying tunnel, side guards, and foam liners. In the past, a three-liner system was commonly used, with liner paper on the left and right sides moving synchronously with the foam body along the exhaust duct, while the bottom liner paper moved forward in sync with the conveyor belt. In the past, the upper part of the foam body was not restricted, resulting in a wasteful arched shape. Subsequently, the Hennecke-Planidiock method (see Picture 4) and the Hennecke flat-top foaming method (see Picture 8-5) were invented. The improved Hennecke flat-top method is now widely used.

Pic 4 Hennecke-Planidiock method

Pic 5 Schematic diagram of Hennecke flat-top foaming process

Both of the aforementioned production methods are equipped with mechanical balance pressure plates on the upper part of the rising foam body to reduce the volume of arched waste generated at the top of the foam body. Currently, the equipment for Hennecke's flat-top foaming often employs four liner papers synchronized to move in the upward, downward, leftward, and rightward directions along with the conveyor belt.

The lining materials for the foam body include specialized liner paper and plastic film. The base material of the liner paper is strong and durable kraft paper, treated with release agents such as polydimethylsiloxane or paraffin, or coated with non-adhesive chemicals like polyethylene. In recent years, some production facilities have begun using cost-effective plastic films like polyethylene, but it's important to ensure that the film does not crease during operation. Regardless of the lining material, it must remain flat and free of folds during operation.

In the foaming section's drying tunnel, the foam body expands and foams on the liner paper of the conveyor belt. Depending on the specific production formulation, the heat generated by the material's reaction or external heat sources are utilized to expedite the foam body's reaction, curing, and solidification, achieving the desired strength and performance for the subsequent process. The drying tunnel is equipped with multiple exhaust devices to remove various harmful gases produced by the foam body. After purification, these gases are released into the atmosphere.

The conveyor belt system for the foam body requires an extremely smooth surface and operates very steadily without any vibrations. The spacing between the side guards can be adjusted within a certain range as needed, allowing the production of rectangular foam bodies of different widths. The width can reach up to 2.2 meters, and the height of the produced foam bodies generally exceeds 1 meter.

After passing through the drying tunnel, although the foam body has not yet reached its maximum performance, it has been shaped. To facilitate subsequent stages of work, an online assembly cutting machine is used to cut the foam body into desired lengths. Following this, post-curing is performed to ensure complete reaction before further processing.

2. Maxfoam down-moving foaming method

The Maxfoam method, also known as the downward foaming method, was invented by Norwegian scientist Leader Berg in 1959. It employs a distinctive approach, where the foam foaming bottom plate moves downward. The fundamental principle involves raising the front end of a movable bottom plate to a position approximately 70% of the anticipated final foam height. This allows the entire bottom plate to be inclined downward. As the poured material rises to around 30% of its foam height, the lower bottom plate moves downward at the foam's rate of expansion. This causes the remaining 70% of the foam's height to expand downward, resulting in a foam body with a rectangular cross-section. The principle and equipment can be seen in Picture 6. Leader Berg used this principle to design and develop the renowned Maxfoam downward foaming process, depicted in Picture 7.

Pic 6 Schematic diagram of the principle of bottom plate moving down method

Pic 7 Schematic diagram of Maxfoam down-moving foaming process

In the development of the Maxfoam production apparatus, Leader Berg initially placed a baffle at the discharge point of the mixed material. This gradually evolved into an elongated downward foaming trough, and the flat plate where the material flowed was transformed into a downward-inclined bottom plate. This alteration changed the foam body's upward expansion during initiation to a downward expansion, leading to the creation of the renowned Maxfoam foaming process. Leader Berg's company has been dedicated to the research, development, production, and sales of flexible polyurethane block foam production processes and equipment, becoming one of the most prominent companies in this field. The basic process flow can be seen in Picture 8.

Pic 8 Maxfoam equipment produced by Hennecke

(1)The cross-section of the produced foam body is in a regular rectangular shape, leading to a significant reduction in waste rate and a high yield of finished products. In traditional processes, waste from edge and corner cuts is approximately 15%. In the Draka edge sliding method, it's around 12%. However, the waste generated by the Maxfoam process is less than 8%. With further improvements, such as using rotating forks, traction, and flattening devices covered with polyethylene film to fully envelop the foam body (see Picture 9), and utilizing the heat generated by the reactants to heat the bottom plate to make the lower skin of the foam thinner, waste can be lowered to 1% to 2%.

Pic 9 Laying polyethylene thin turning fork (a) device (b) and flattening device (c)

(2) The equipment is well-designed, precisely manufactured, accurately controlled, with a long lifespan, low production costs, and typically requires only 3 to 4 personnel for operation, with low maintenance costs.

(3) The unique foaming process ensures that the produced foam body has a uniform and consistent density, fine cell structure, and excellent quality.

(4) A typical control panel or an enhanced computer system monitors the entire production process with precision.

(5) The range of applicable raw materials is extensive, including both polyether and polyester types. Various types of foam bodies can be produced, including standard flexible foam as well as high-resilience foam, flame-retardant foam, filled foam, viscoelastic foam, and foam produced using carbon dioxide foaming. 

In 1960, Leader Berg established his own company, Laader Berg AS, dedicated to the research and production of continuous polyurethane foam production equipment. The key components of the basic MaxformTM foaming machine are the Multi Trough (Picture 10) and the drop plate. As shown in the equipment schematic in Picture 11, the mixed materials are conveyed through multiple pipes to the bottom entry of the multi-trough. The material begins to react in the multi-trough and flows onto the bottom liner paper sliding on the inclined drop plate just before the emulsification of the mixed liquid. The foam from the multi-trough evenly overflows and spreads between the two side walls of the drop plate. The overflow volume of the multi-trough can be adjusted based on the foaming formula and production volume, and its outlet height is set at 70% of the final foam height. 

Simultaneously, the angle, quantity, length, and width of the inclined drop plate can be adjusted according to the formula and production volume, ensuring that the foam body completes its full expansion process when it reaches the horizontal conveyor belt. During the downward flow of the foam body in the foaming channel of the drop plate, the friction between the foam body and the side walls is eliminated by downward gravity, resulting in a more uniform and smooth foam structure on both sides of the foam body. The foam body discharges the waste gases produced during production in the foaming channel, completes the maturation of the foam body, and can then proceed to the cutting process.

Pic 10 Multiple slots for Maxfoam foam machine multi trough

Pic 11 Basic MaxfoamTM Schematic

Our company also produces this kind of production line on the basis of this foaming method. The introduction reference is as follows (see Picture 12)

Technical parameters of SAB-CF02 automatic horizontal continuous foaming production line produced by Sabtech Technology

1. Main machine specification: total length 42m × width 6m × 4m

2. Foam sponge width: 915mm ~ 2350mm

3. Foaming height: below 1300mm

4. Foaming speed: 1500rpm ~ 7000rpm

5. Maximum output: 350kg / min

6. Spraying mode: The way of trough device, with inverter controlling

7. Foam box specification: L21m * W4.5m * H3m

8. Oven inner conveyer line (standard): L27m * W2.6m * H0.8m

9. Oven side links(standard) L21m * H1.3m

10. Drop frame: 7 sections of electric adjustment height / 0.2KW deceleration motor chain is used to drive rack adjustment between each section of plate

11. Side paper lifting device: front and rear electric movement, lift lever height electric adjustment, left and right-side independent control.

12. Side film collect and release system: the side film and lifting film releasing device is equipped with motor drive, the side film adopts magnetic powder clutch device to automatically reel in.

13. Bottom paper storage system.

14. Exhaust fan: 3kw * 2 sets (excluding exhaust pipe). 

15. Constant temperature system: 20HP air-cooled cold and hot thermostat. Proportional valve is installed at the front inlet of tank coil, and raw material temperature is controlled and set.

16. Powersupply:3phrase 380V 50HZ

Figure 12 Sabtech Technology Limited horizontal continuous foaming unit3

3. Vertical Foam Method

In 1971, the UK-based company Hyman Development Corporation developed a unique vertical foam process technology and equipment. The apparatus mainly consists of a material storage tank system, metering conveying system, mixing injection system, barrel-shaped foaming device, heating and foam lifting device, as well as a cutting mechanism (see Picture 13).

Pic 13 Schematic diagram of vertical foaming equipment

The material storage tank system consists of five main components: raw material tanks (equipped with temperature control and stirring devices) for PPG, with TDI as the primary raw material, mixed with water, oil, amine catalyst, additives, MC foaming agent, and organic tin catalyst. Their metering and conveying systems generally use gear pumps driven by stepless speed-regulated motors, and flow meters can also be added to enhance metering accuracy. Low-pressure, agitating-type mixing heads are typically chosen. Once the materials are mixed, they are injected through pipelines from the bottom into the conical foam bucket. The foam bucket is pre-fitted with continuous sheets of polyethylene film. As the mixed materials react and foam, they initially move horizontally, filling the conical cross-section and gradually rising as the cross-section expands, eventually filling the polyethylene film-lined bucket and moving upward into the heating section. An electric heating system surrounds the heating section to expedite the foam maturation process.

The foam's ascent is facilitated by vertical conveyors equipped with fine needles (10-15mm in length). Multiple such conveyors are arranged around the entire foam body, with their fine needles embedded in the foam of a certain strength. As the conveyor belt rotates, the foam is gradually lifted. The upper part of the equipment is equipped with a cutting machine and a linked clutch mechanism that activates the cutting machine when the foam body reaches the designated height. The cut foam pieces are transported along an inclined slide to the post-maturation chamber. 

This process can produce foam bodies with either square or circular cross-sections, simply by changing the shape of the foam bucket. During continuous production, the foam's color can be changed online, with a transition zone of only 150mm. This not only facilitates easy color changes but also maintains a high yield of finished foam products. The density and hardness performance on the foam's cross-section are consistent, and the foam's skin thickness at the edges is thin, resulting in low waste rates. Importantly, vertical foaming equipment occupies a smaller footprint, only a quarter of that of traditional horizontal foaming equipment, making it suitable for small and medium-sized enterprises. The products are not only suitable for general soft foam products but also the sliced circular foam bodies are particularly suitable for use as clothing lining materials.

The vertical foaming process imposes stricter requirements on aspects such as raw materials, formulations, and production process adjustment and control, compared to the production process of horizontal block foams. Precise control of various process parameters such as raw material temperature, formulation ratios, foam discharge rate, air injection rate, mixing speed, maturation section temperature, and traction speed is necessary to produce high-quality foam. In actual production, the following issues are prone to occur and must be addressed:

1.High Foam Closed Cell Rate or Shrinkage:

This can result from excessive use of organic tin catalyst, leading to rapid gelation during foaming and excessive growth of pore wall strength. Additionally, an excess of foam stabilizer can hinder the formation of open-cell foam structure due to its excessive stability.

2.Foam Body Cracking:

Foam body cracking is often due to errors in formulation or metering. Insufficient amounts of organic tin catalyst and foam stabilizer can lead to decreased reactivity. Mechanical factors, such as the presence of impurities, oil contamination within the foam body, and fluctuations in traction speed, can also contribute to extensive foam body cracking.

3. Large Bubble Cavities in Foam Body:

When large bubble cavities appear in the foam body, it is important to thoroughly inspect the following aspects: When there is a regular distribution of air bubbles, check whether there are any air leakage issues in the mixing chamber, feed pipes, and other equipment. If there are a few conical large bubbles present, it could be due to excessively high raw material temperature, causing the foaming agent to vaporize more easily. When the foam body exhibits irregularly distributed large air bubbles, the main cause could be excessive mixing speed resulting in a higher amount of entrapped air. Typically, with a well-sealed mixing head, the mixing speed should be controlled within the range of 2500 to 3000 rpm. If large perforations or interconnected bubbles appear in the foam sheet without a clear network structure, it might be due to excessive air input into the mixing head.

4.The Foam Body Sliding Downward：

This issue should be considered from several aspects, including formulation errors, excessive foaming time, insufficient foaming, excessively low maturation temperature, and improper coordination of the traction conveyor. It is a problem that can easily occur in the initial stages of equipm

Pic 14 Schematic diagram of the production process of the polyurethane flexible foam pressure-swing foaming continuous production line device

(1) Open the middle chamber door 3a and close the exit chamber door 3b. Activate the pressure control system 4a4b to bring the pressure in the entire channel to the set pressure value. The typical pressure range is 50 to 150 kPa (0.5 to 1.5 atm).

(2) Start the foaming machine, and the mixed material enters the overflow trough in the enclosed channel and flows to the drop plate for foaming under the set pressure environment.

(3) After the foam body is preliminarily cured and shaped to a certain length, the cutting machine operates to cut it.

(4) The cut foam body enters the post-area of the channel. Close the middle chamber door, adjust the pressure in the rear area to be equal to the ambient pressure, open the exit chamber door, and transport the foam body to the curing area to complete the curing. At the same time, the exit chamber door should be closed immediately, and the pressure regulation device should be activated immediately to equalize its pressure with the pressure in the entire channel. Then, open the middle chamber door to accommodate the next cut foam body.

This production line is monitored by highly automated computers, with segment control of the channel, cycle switching, and pressure adjustment system. Depending on the sealed channel, whether it's a vacuum or pressure vessel, it can produce foam bodies with rectangular or circular cross-sections. Based on this continuous production line, intermittent production lines with box-type variable pressure foaming have also been developed. Although the production efficiency is high, the control system is complex, and the equipment is bulky, with sealed channel lengths often exceeding hundreds of meters, resulting in significant investment. 

The above provides an introduction to the horizontal continuous production line for flexible polyurethane foam blocks. Hope it can help you how to choose polyurethane flexible foam continuous production line. Welcome to leave a comment and discuss with me more about polyurethane foam.

In polyurethane flexible foams, dichloromethane (MC) is often used to adjust the density and hardness of the foam. With a boiling point of only 40.4°C, during foaming, the reaction of water and TDI generates a large amount of heat, causing MC to evaporate into gas, thus expanding the foam body and reducing foam density.

The vaporization of MC consumes a lot of heat, which can affect the foaming process of the foam in some cases. The following two figures show the changes in the maximum foam temperature and the time to reach it after adding different amounts of MC to a specific formula.

From the charts, it can be observed that after adding MC, the maximum foam temperature decreases significantly, and the time to reach the maximum temperature also increases.

These are just changes in data, but how do they manifest during the actual foaming process? To understand this, let's briefly look at the polyurethane reaction process.

The main reaction in polyurethane foaming is the reaction of water and isocyanate to produce carbon dioxide and amine, and the reaction of polyether polyol and isocyanate to produce polyurethane. However, there are many secondary reactions, summarized as reactions generating urethane and reactions generating urea.

Secondary reactions change the molecular structure of the polymer from linear to cross-linked. Due to different reaction conditions and raw materials, the structure of polyurethane can vary greatly. In general, the more secondary reactions, the more complex the cross-linked structure, resulting in increased hardness and improved tear strength. Of course, the resistance to yellowing also improves, but that's another topic. Increasing the foaming index will strengthen secondary reactions.

Having said so much, what does this have to do with MC? Secondary reactions are all endothermic reactions, requiring heat absorption. However, the vaporization of MC also requires a large amount of heat, thus creating a competitive relationship. Adding a large amount of MC will significantly weaken secondary reactions, increasing the proportion of linear structures in the foam, making it softer, and decreasing thermal plasticity.

Even in colder temperatures during winter, attention should be paid to this issue. Properly increasing the water content in the formula to generate more heat helps maintain the physical properties of the foam without significant changes.

The reaction of PU foam is based on two main chemical components: polyether polyols and isocyanates, along with other additives including water, dichlorodifluoromethane, foam stabilizers, and catalysts. These materials are instantly and vigorously mixed, reacting to form foam, a process that generates a considerable amount of heat.

Foam plastic is a porous material with a large surface area. While the heat generated at the edges of the foam can dissipate, the heat in the central part, due to the insulation effect of the foam, is more difficult to remove. In a typical reaction, the heat released raises the temperature of the center of the foam block to achieve curing. It has been observed that within 2 to 6 hours after foaming, temperatures can rise to 140-160°C, and sometimes even higher, around 180°C. If the temperature continues to rise, it can lead to core burning, smoking, and even spontaneous combustion.

Additionally, prolonged exposure of polyurethane foam to sunlight can trigger an auto-oxidation reaction, causing polymer degradation, discoloration, embrittlement, and a decrease in physical properties, rendering it unusable. Since the industrialization of polyurethane, core burning and aging have been hot topics of research and concern in the polyurethane industry.

Antioxidants are crucial additives in polyurethane foam production. Proper antioxidants prevent the decomposition of polyols, reduce the formation of by-products, decrease the risk of core burning, and can delay thermal oxidative aging during product use, thereby extending its lifespan. Commonly used antioxidants for PU foam are typically liquid and fall into three categories: aromatic amines (such as 5057), hindered phenols (such as 1135), and phosphite esters (such as PDP). For applications with low color requirements, a combination of aromatic amines and hindered phenols is generally used, while applications with higher color requirements may use a combination of hindered phenols and phosphite esters.

Furthermore, if products are frequently exposed to sunlight, a certain amount of UV stabilizers should be added to improve lifespan and resistance to yellowing. UV stabilizers mainly consist of UV absorbers and hindered amine light stabilizers (HALS). UV absorbers, such as benzotriazoles, benzophenones, and triazines, absorb harmful UV radiation and convert it into heat through intramolecular hydrogen bond transfer or cis-trans isomerization. HALS refers to amines with two methyl groups on each α-carbon atom, which, after photooxidation, transform into nitroso radicals. These radicals are considered stable components that can capture free radicals, regenerate nitroso radicals by reacting with peroxide radicals. UV blocking agents include carbon black, zinc oxide, titanium dioxide, and other pigments, which are used as colorants. These agents utilize their high dispersibility and covering power to reflect harmful UV radiation, protecting the polymer.

Have you ever wondered how polyurethane plastic foam is formed? In the previous article, we revealed the basic reactions behind it: isocyanates, polyether (or polyester) polyols, and water, all work together to create this magical substance. So, does this mean that in actual production, we only need these three raw materials? The answer is far from it. In our actual production process, in order to more precisely control the reaction rate and produce products with excellent performance, we often need to harness the power of various additives. These additives not only have wide-ranging applications but also can play a huge role in making our production process more efficient and stable.

Surfactants / Silicone Oil

Surfactants, also known as silicone oil, are also called foam stabilizers. In the production process of polyurethane foam, its role is crucial. The basic duty of silicone oil is to reduce the surface tension of the foaming system, thus improving the miscibility between components, adjusting the size of bubbles, controlling the bubble structure, and enhancing foam stability. Furthermore, it also bears the responsibility of preventing foam collapse. Therefore, it can be said that silicone oil plays an indispensable role in the production of polyurethane foam.

Catalysts

Catalysts play a crucial role in the synthesis process of polyurethane, mainly by accelerating the reaction between isocyanates, water, and polyols. This reaction is a typical polymerization reaction. Without the presence of catalysts, this reaction may proceed very slowly or even not at all. Currently, catalysts on the market are mainly divided into two types: amine catalysts and organic metal catalysts. Amine catalysts are compounds based on nitrogen atoms, which can effectively promote the polymerization reaction of polyurethane. Organic metal catalysts, on the other hand, are compounds that particularly affect the reaction between polyols and isocyanates in the formation of polyurethane, usually organotin compounds. The characteristic of these catalysts lies in their ability to precisely control the reaction process, resulting in a more uniform and stable final product.

Blowing Agents

Blowing agents are substances that generate gas during the polyurethane reaction and help form foam. Depending on the way gas is generated, blowing agents are usually divided into chemical blowing agents and physical blowing agents. Chemical blowing agents refer to substances that undergo chemical changes during the reaction, generate gas, and promote foam formation. Many common substances in our daily lives are actually chemical blowing agents, such as water. Physical blowing agents, on the other hand, are substances that generate gas through physical means. For example, dichloromethane (MC) is a common physical blowing agent.

Other Additives

Relying solely on basic raw materials is far from enough to make products have outstanding performance. In order to meet various needs, other additives are cleverly incorporated into the production process, and their roles should not be underestimated. For example, flame retardants can add flame resistance to products, crosslinking agents can enhance their stability, colorants and fillers can give products a more colorful appearance and texture, and various other additives with different functions are also playing their roles. It is these carefully selected additives that comprehensively improve the performance of the products and bring users a better user experience.

1. What are the different types of commonly used isocyanates structurally classified as?

   Answer: Aliphatic: HDI; Cycloaliphatic: IPDI, HTDI, HMDI; Aromatic: TDI, MDI, PAPI, PPDI, NDI.

2. What are the various types of commonly used isocyanates? Provide their structural formulas.

   Answer: Toluene diisocyanate (TDI), Diphenylmethane-4,4'-diisocyanate (MDI), Polymeric diphenylmethane diisocyanate (PAPI), Liquid MDI, Hexamethylene diisocyanate (HDI).

3. What do TDI-100 and TDI-80 signify?

   Answer: TDI-100 refers to toluene diisocyanate composed entirely of the 2,4 structure; TDI-80 denotes a mixture comprising 80% of the 2,4 structure and 20% of the 2,6 structure.

4. What are the distinguishing characteristics of TDI and MDI in the synthesis of polyurethane materials?

   Answer: In terms of reactivity, 2,4-TDI exhibits several times higher reactivity than 2,6-TDI due to the 4-position NCO being relatively far from the 2-position NCO and methyl, resulting in minimal steric hindrance. In contrast, the reactivity of 2,6-TDI is significantly influenced by steric hindrance from neighboring methyl groups.

   Both NCO groups in MDI are relatively distant from each other and unsubstituted, thus displaying significant reactivity. Even if one NCO participates in a reaction, reducing the activity of the remaining NCO, overall reactivity remains high. Therefore, the reactivity of MDI-based polyurethane prepolymers is greater than that of TDI-based prepolymers.

5. Which types among HDI, IPDI, MDI, TDI, and NDI exhibit better resistance to yellowing?

   Answer: HDI (belonging to non-yellowing aliphatic isocyanates) and IPDI (polyurethane resins made from it exhibit excellent optical stability and chemical resistance, commonly used for manufacturing high-grade non-yellowing polyurethane resins).