Many factors affect the foaming process and final product quality when manufacturing polyurethane flexible foam. Among these, natural environmental factors such as temperature, air humidity, and atmospheric pressure play crucial roles. These factors significantly influence foam density, hardness, elongation rate, and mechanical strength.

1. Temperature:

Polyurethane foaming reaction is highly sensitive, with temperature being a key control factor. As material temperature rises, the foaming reaction accelerates. In sensitive formulations, excessively high temperatures can pose risks like core burning and ignition. Generally, it's essential to maintain consistent temperatures for polyol and isocyanate components. Increasing temperature leads to a corresponding decrease in foam density during foaming.

Particularly in summer, elevated temperatures increase reaction speed, resulting in decreased foam density and hardness, increased elongation rate, yet enhanced mechanical strength. To counter hardness reduction, adjusting the TDI index is advisable. Manufacturers must adjust process parameters according to seasonal and regional temperature variations to ensure product quality stability. 

2. Air Humidity:

Air humidity also affects the foaming process of polyurethane flexible foam. Higher humidity causes reactions between isocyanate groups in the foam and airborne moisture, leading to reduced product hardness. Increasing TDI dosage during foaming can compensate for this effect. However, excessive humidity can raise curing temperatures, potentially causing core burning. Manufacturers need to carefully adjust foam process formulations and parameters in humid environments to ensure product quality and stability.

3. Atmospheric Pressure:

Atmospheric pressure is another influencing factor, especially in areas at different altitudes. Using the same formulation at higher altitudes results in relatively lower foam product density. This is due to atmospheric pressure variations affecting gas diffusion and expansion during foaming. Manufacturers operating in high-altitude regions should take note of this and may need to adjust formulations or process parameters to meet quality requirements.

In conclusion, natural environmental factors significantly impact the foaming process and final product quality of polyurethane flexible foam. Manufacturers must adjust process parameters based on seasonal, regional, and environmental conditions to ensure stable foam density, hardness, and mechanical strength, meeting customer demands and standards.

Aluminum Hydroxide

Also known as hydrated alumina. The aluminum hydroxide used as a fire retardant is mainly @-tri-hydrated alumina. It appears as a white fine crystalline powder with an average particle size of 1-20 micrometers. Its relative density is 2.42, refractive index is 1.57, and 30% slurry pH is 9.5-10.5. The dehydration initiation temperature is 200 degrees Celsius, with an absorption heat of 2.0 KJ/G.

During combustion, it releases a large amount of chemically combined water, absorbs a considerable amount of heat, slows down the polymer's thermal degradation rate, reduces the material surface temperature, delays and suppresses the combustion of the substrate. It will generate a large amount of steam on the substrate surface, diluting the oxygen in the combustion zone, reducing the concentration of smoke and toxic flammable gases. The aluminum oxide generated during combustion can promote the formation of a carbonized protective layer on the polymer surface.

Melamine

Commonly known as melamine, it is a white monoclinic crystal with low toxicity, non-flammable, and a melting point of 354 degrees Celsius. It undergoes endothermic sublimation and rapid decomposition under high heat. At temperatures between 250-450 degrees Celsius, it can absorb a large amount of heat and release nitrogen during decomposition, slowing down the material's combustion rate. At the same time, it forms a carbonized barrier layer on the substrate surface, acting as a fire retardant. However, there are some dispersion problems, so it needs to be used in combination. When used as a fire retardant, high-temperature decomposition can produce toxic cyanide gas.

Organophosphorus Flame Retardant

Tris(1,3-dichloro-2-propyl)phosphate (TDCPP)

A pale yellow transparent viscous liquid. It contains 7.2% phosphorus and 49.4% chlorine, with a flash point of 251.7 degrees Celsius, ignition point of 282 degrees Celsius, and spontaneous combustion temperature of 514 degrees Celsius. It starts to decompose at 230 degrees Celsius and is soluble in alcohols, benzene, carbon tetrachloride, etc. When used at 5%, it can achieve self-extinguishing properties, and at 10%, it can make the material self-extinguish or non-flammable, while also having water resistance, light resistance, and antistatic properties.

Fire Retardant Polyether Polyol

1. Formula Ingredients:

Polyether polyol 3050: Mn3000;

Flame-retardant polyether polyol: Hydroxyl value 28, flame-retardant solid mass fraction 23%;

Silicone oil: L580

Triethylene diamine solution: Mass fraction 33%;

Tin octoate solution: Mass fraction 33%;

TDI: Industrial grade

Testing Conditions:

1. Fast foaming is taken from the center of the foam, while molded foam samples are taken from the central part or for whole sample testing.

2. Newly made foam should be matured for 72 hours in its natural state before sampling. Samples should be placed in a constant temperature and humidity environment (as per GB/T2918: 23±2℃, relative humidity 50±5%).

Density: Density = Mass (kg) / Volume (m3)

Hardness: Indentation Load Deflection (ILD), Compression Load Deflection (CLD)

The main difference between these two test methods is the loading area of the foam plastic. In the ILD test, the sample is subjected to a compressed area of 323 cm2, while in CLD the entire sample is compressed. Here, we will only discuss the ILD test method.

In the ILD test, the sample size is 38*38*50mm, with a test head diameter of 200mm (with a round corner of R=10 on the bottom edge), and a support plate with 6mm holes spaced 20mm apart. The test head loading speed is (100±20) mm/min. Initially, a pressure of 5N is applied as the zero point, then the sample is compressed to 70% of its thickness at the zero point, and unloaded at the same speed. This loading and unloading is repeated three times as pre-loading, then immediately compressed at the same speed. The compression thicknesses are 25±1% and 65±1%. After reaching the deformation, hold for 30±1s and record the relative indentation value. The recorded value is the indentation hardness at that compression level.

Additionally, 65% ILD / 25% ILD = Compression Ratio, which is a measure of foam comfort.

Tensile Strength, Elongation at Break: Refers to the maximum tensile stress applied during the tensile test until fracture, and the percentage elongation of the sample at fracture.

Tensile Strength = Load at Fracture / Original Cross-sectional Area of Sample

Elongation at Break = (Fracture Distance - Original Distance) / Original Distance * 100%

Tear Strength: Measures the material's resistance to tearing by applying specified tearing force on a sample of defined shape.

Sample size: 150*25*25mm (GB/T 10808), with the sample thickness direction as the foam rise direction. A 40mm long incision is made along the thickness direction (foam rise direction) at the center of one end of the sample. Measure the thickness along the sample thickness direction, then open the sample and clamp it in the test machine fixture. Apply load at a speed of 50-20mm/min, using a blade to cut the sample, keeping the blade at the center position. Record the maximum value when the sample breaks or tears at 50mm.

Tear Strength = Maximum Force Value (N) / Average Thickness of Sample (cm)

Usually, three samples are tested, and the arithmetic mean is taken.

Resilience: Measures the foam's rebound performance by allowing a given diameter, weight steel ball to freely fall onto the surface of the foam plastic sample from a specified height. The ratio of the rebound height to the steel ball's drop height indicates the foam's resilience.

Test Requirements: Sample size 100*100*50mm, the ball drop direction should be consistent with the foam usage direction. The steel ball size is ∮164mm, weight 16.3g, and it drops from a height of 460mm.

Resilience Rate = Steel Ball Rebound Height / Steel Ball Drop Height * 100%

Note: Samples should be horizontal, steel ball should be fixed before dropping (static), each sample is tested three times with 20s intervals, and the maximum value is recorded.

Compression Permanent Deformation: In a constant environment, the foam material sample is maintained under constant deformation for a certain period, then allowed to recover for a period of time, observing the effect of the deformation on the sample's thickness. The ratio of the difference between the initial thickness and final thickness of the sample to the initial thickness represents the foam plastic's permanent compression deformation.

Compression Permanent Deformation = (Initial Thickness of Sample - Final Thickness of Sample) / Initial Thickness of Sample * 100

Fire Resistance

VOC (Volatile Organic Compounds)

Beginners are concerned that if the settling plate is not adjusted properly, the liquid flowing out of the nozzle may cause front surging or back surging, affecting the foaming process. Within two minutes after starting the machine, the reaction speed gradually increases, sometimes requiring adjustments to the settling plate. Adjustments to the settling plate are more critical in low-density and high-moisture-content (MC) formulas.

TDI (Toluene Diisocyanate) flow rate can be calculated to correspond to the scale value, but it is recommended to actually measure the TDI flow rate during the first foaming. Flow rate is too important; if the flow rate is not accurate, everything else will be a mess. It's best to rely on the simplest and most intuitive method of measuring the flow rate.

When mixing powders, the mixed stone powder should be left overnight and production should start the next day. For ingredients containing melamine and stone powder, it is recommended to first mix melamine with polyether for a period of time before adding the stone powder.

Foam machine formulas with long mixing chamber in the machine head or more teeth on the stirring shaft usually have less amine and lower material temperature. Conversely, foam machine formulas with short mixing chamber in the machine head or fewer teeth on the stirring shaft usually have more amine and higher material temperature.

For the same formula, when switching between dual-spray swivel heads and single-spray swivel heads with similar nozzle cross-sectional areas, the requirements for mesh thickness and layers are similar.

For the calibration of minor material flow, one method is to measure the return flow of the minor material, and the other is to calibrate it by dividing the total amount used by the foaming time. When there is a significant difference between the two calibration methods, rely on the data from the second calibration method.

Formulas for high-quality soft foam are usually within an unstable range, such as a low TDI index, low water-to-MC ratio, low T-9 dosage, and low silicone oil dosage.

1. Adjust Formulation:

Control the amount of water to not exceed 4.5 parts, and if necessary, use low-boiling-point liquid compounds as auxiliary foaming agents to replace some water. Pay attention to the amount of water in the formulation, which must not exceed 5 parts. The highest safe temperature rise point for low-density foam is 160°C, and it must not exceed 170°C.

2. Strictly Control the Accuracy of Component Measurement:

During continuous block foam production, adjust the discharge speed of the mixing head material and the conveyor belt speed to coordinate them. Avoid phenomena such as under-foaming materials flowing into the bottom of already foaming materials due to slow conveyor belt speed or excessive discharge, which can prevent normal foaming, resulting in collapse. Collapsed materials are not easily able to produce localized "gas species," leading to localized heat accumulation and increased risk of scorching. In actual production, poor process parameters may result in small yellow scorching lines appearing at the bottom of foam blocks.

3. Avoid Compressing the Newly Produced Foam:

This is because compressing the foam before it is fully cured affects the foam network and structure. It also prevents heat accumulation due to compression, increasing the risk of self-ignition of new foam. Especially during the most sensitive stage of foam rising, any operational errors and vibrations, such as sudden movements caused by tight conveyor belt chains or excessive folding of isolation paper and belt shaking, can cause compression of immature foam, leading to scorching.

4. Strictly Observe the Curing and Storage Process of Foam:

For the production of polyurethane soft block foam, the curing process of new foam is a high-risk period for fire accidents. Due to the high internal temperature and long duration of heat dissipation in large block foams, the time to reach the highest internal temperature is usually about 30 to 60 minutes, and it takes 3 to 4 hours or longer for it to slowly decrease. During this time, the new foams have left the production line and entered the curing and storage phase, which is easily overlooked. Without proper monitoring measures, it can easily lead to fires. There have been reports that when producing block soft foam with a density of 22kg/? using a polyol with a molecular weight of over 5000, 4.7 parts of water, and 8 parts of F-11 with a TDI index of 1.07, a small amount of light yellow smoke was observed 2 hours later. Although the external temperature of the foam was not high, the interior was in a very dangerous initial stage of decomposition, with a temperature of around 200-250°C, already beginning to self-ignite.

5. To Prevent Self-Ignition of Foam:

Newly produced foam should be cured and stored, not exceeding 3 layers when stacked, with a spacing of more than 100mm between layers, preferably placed separately. The curing and storage phase should have dedicated personnel for enhanced monitoring, such as measuring the internal temperature of the foam every 15 minutes for at least 12 hours, or even longer, before normal storage. For foams that may generate high temperatures, large foam blocks should be cut horizontally (e.g., with a thickness of 200mm) to facilitate heat dissipation. When smoke or self-ignition is detected, use water spray or fire extinguishers, and do not move the foam or open doors and windows indiscriminately to prevent increasing airflow and exacerbating the fire.