In December 2021, we received an inquiry from Mr. Hairun in Malaysia. Mr. Hairun is a mattress manufacturer in need of producing rebonded foam. He had limited knowledge about machine usage and selection and had no prior experience with the production process. Therefore, he required guidance from experts who could assist him from the ground up.



We systematically explained the principles of foam production to Mr. Hairun, along with the necessary materials and equipment. We also took him on a tour of our factory to provide a clear understanding of the entire production process.



After understanding Mr. Hairun's preferences for the rebonded foam, including density, softness, and market prices, we offered him the most suitable foam production solution. We also provided him with information on foam production costs and compared raw material prices for his reference.



Based on the client's needs, budget, and existing factory layout, we devised a cost-effective machine configuration and layout plan for his facility, including an assessment of startup costs.



Once the machines were successfully installed, our team of engineers provided Mr. Hairun with one-on-one foam production training. When he successfully produced the foam he desired for the first time, he called us and said, "I am happy with crying, thank you very much!" Afterward, he purchased a batch foam machine from us and continued to reorder foam chemical materials from our company.

There are many reasons for the cracking of polyurethane foam, including both chemical and mechanical factors. During production, it is important to stop and inspect, making sure to eliminate the phenomenon of cracking. Below are some insights we have summarized based on years of production experience, hoping to inspire everyone.

1. Sudden Changes

Sudden changes in the speed of the conveyor, variations in catalyst usage, or irregular operation of the conveyor can cause the foam to crack. Carefully and gradually adjust the above situations. A significant change in the speed of the conveyor can lead to large cracks in the foam blocks.

2. Polyethylene Film

If the film stops moving for some reason, the foam will come into contact with the static surface, leading to cracking. If this situation occurs, check the winding roller of the rewinder and examine the separation of the film in the curing area.

3. Foam Forming Around Certain Substances

Foam tends to form around certain substances, especially in the feed chute, which can easily cause cracking.

Before production, ensure there are no residues or debris left in the assembly of the mixing head, feeding hose, and discharge chute.

4. Excessive Amine

When there is insufficient stannous octoate, excessive amine can lead to the same effect and accelerate the rise time. Therefore, the dosage of amine must be reduced.

5. Insufficient Stannous Octoate

Due to the faster foaming reaction compared to the polymerization reaction, some foam may flow, leading to cracks. Therefore, the amount of stannous octoate must be increased.

6. Silicone Oil

Foaming becomes unstable and prone to rupture, potentially forming "depressions" on the foam, so it is necessary to increase the dosage of silicone oil.

7. Structure of Small Air Bubbles

Thin foam walls due to foaming can cause cracking. To address this comprehensively: reduce the air content, decrease the speed of the mixing head, or increase the pressure of the mixing head. It is also necessary to change the dosage of stannous octoate catalyst.

The production of block-shaped soft foam typically utilizes the batch foam machine foaming process, a gap-type production method. This method evolved from manual foaming in laboratories. The process involves immediately pouring the mixed reaction materials into an open mold resembling a wooden or metal box, hence the name "boxed foam." The molds (boxes) for boxed foam can be rectangular or cylindrical. To prevent the foam block from forming a domed top, a floating cover plate can be placed on the top of the foam during foaming. The cover plate stays closely attached to the top of the foam and gradually moves upward as the foam rises.



The main equipment for boxed foam production includes: 1) Electric-mechanical stirrer, mixing barrel; 2) Mold box; 3) Weighing tools such as scales, platform scales, measuring cups, glass syringes, and other measuring devices; 4) Stopwatch for controlling mixing time. A small amount of mold release agent is applied to the inner walls of the box to facilitate easy removal of the foam.



The advantages of producing soft foam using the boxed foam method include: low equipment investment, small footprint, simple equipment structure, easy and convenient operation and maintenance, and flexible production. Some small and underfunded domestic and township enterprises use this method to produce polyurethane soft foam. Boxed foam molding is a non-continuous production method for soft foam, so the production efficiency is lower than continuous methods, and the equipment is mostly manually operated, resulting in higher labor intensity. Production capacity is limited, and there is a greater loss in cutting foam plastics. The process parameters for boxed foam should be controlled within a certain range because even with the same formula, the foam properties may not be the same when different process parameters are used. The raw material temperature should be controlled at (25±3) degrees Celsius, mixing speed at 900 to 1000r/min, and mixing time at 5 to 12 seconds. The mixing time of the polyether and additives mixture before adding TDI can be flexibly adjusted depending on the situation, and after adding TDI, a mixing time of 3 to 5 seconds is sufficient, with the key being thorough mixing after TDI addition.



During boxed foam molding, attention should be paid to the following aspects:

1) Prepare before production, including material temperature and machine equipment inspection;

2) Measure as accurately as possible;

3) Control the mixing time appropriately;

4) Pour the mixed material liquid quickly and steadily, avoiding excessive force;

5) Ensure the box is placed steadily, with the bottom paper flat, to avoid uneven material flow during pouring;

6) When the foam rises, gently press the cover to ensure the foam rises smoothly;

7) Additives should be used as specified, and pre-mixed materials should not be left for too long.



Three types of foam equipment have emerged in boxed foam molding. Initially, various raw materials were weighed into a container according to the formula, mixed with a high-speed mixer, and poured into the box mold for foaming and shaping. This method often resulted in residue in the mixing container. An improved method used a metering pump to transport the raw materials to the mixing barrel for uniform mixing. A mechanical device automatically closed the bottom of the barrel, and compressed air was used to press the material into the foaming box for shaping. Both of these methods could create eddies due to the rapid influx of materials into the box, which might cause defects or depressions in the foam products. The most reasonable boxed foam device is to place a bottomless mixing barrel directly in the center of the foaming box. A metering pump delivers the various raw materials needed for foaming into the mixing barrel. After mixing for a few seconds, the lifting device raises the mixing barrel out of the foaming box, allowing the foaming material to flow smoothly over the entire box bottom. This prevents foam cracking due to material eddies, and ensures relatively uniform height throughout the foam.



A pressure device can be added to the expanding foam material to produce flat-topped foam, reducing waste during cutting. This device is suitable for the production of polyether-type polyurethane soft foam and high rebound soft block foam. For polyvinyl acetate polyurethane blocks, this method cannot be used due to the high viscosity of the material, and continuous methods are generally employed.

The internal temperature of foam is as indispensable as vitality is to a person. If the post-cure temperature of the sponge is too low, its physical properties will not be optimal, and there will be significant fluctuations in these properties.



Once the foam is well developed, its internal temperature rapidly rises to over 120 degrees Celsius due to the exothermic reaction occurring under poor heat dissipation conditions, becoming one of the fire hazard risks.



The internal temperature of the foam is crucial for forming its superior properties. Foam matured at specific external temperatures exhibits exceptionally superior physical properties like tensile strength. Some calculate the foam temperature through formulas, while others use software to input formulas and automatically calculate the internal temperature of the foam. So, what factors influence the internal temperature of the foam? Is it significant to know these factors? It's akin to how modern phone cameras are high-resolution, but does that render professional photography useless? Are adjustments like aperture, focal length, and exposure time pointless? To better control things, one must grasp more of the key variables of that thing. Let's start with basic principles to understand the changes in internal foam temperature.



First, let's grasp a few basic rules.



The temperature of a space is directly proportional to the amount of heat energy injected into that space and inversely proportional to its size.

For example, if 10 kilojoules of heat are distributed in an 8-liter space, the temperature of that space is 20 degrees Celsius. If the same 10 kilojoules of heat are distributed in a 4-liter space, the temperature becomes 40 degrees Celsius.

The amount of heat input is directly proportional to the heat input value and the speed of heat input.

For instance, if 100 kilojoules of heat are released at speed "v," the heat input is "A." If the same 100 kilojoules of heat are released at 2v speed, the heat input becomes 2A.

The size of a space is directly proportional to the absolute temperature.

For example, a 1-liter space at 0 degrees Celsius becomes 1.366 liters at 100 degrees Celsius because (273.15 + 100)/(273.15 + 0) = 1.366.

The size of a space is inversely proportional to atmospheric pressure.

The lag in methane vaporization needs to be considered.

Next, let's examine how fine-tuning the formula affects the internal foam temperature.



Since this is fine-tuning, we'll approximate that the surrounding environment remains unchanged before and after the adjustments. Let's consider the effects of adjusting water and methane on the internal foam temperature.

For example, if a formula increases methane by 5%, we can be certain that the internal foam temperature decreases because methane vaporization absorbs heat, reducing the heat input to the foam, and increasing the space to accommodate heat. Similarly, if the water content is increased by 5%, the added water releases heat upon injection into the foam, raising the heat input, and the reaction of the added water generates gas, increasing the space for heat. So, does the internal foam temperature increase or decrease in this case? Experience indicates that the internal foam temperature increases. This suggests that the increased heat input due to this change contributes more to the increase in internal foam temperature than the gas produced by water diluting the temperature.



The changes involving foam index, heat release, and heat dissipation all increasing can make it difficult to intuitively guess whether the internal foam temperature will rise or fall. One might need to insert a probe after foaming to compare internal temperatures or calculate to reach a conclusion.



For calculations, several formulas (algebraic expressions) derived from the earlier basic rules are needed, along with some data: the heat released when water reacts with TDI to form carbon dioxide in kilojoules per mole, the heat absorbed during methane vaporization in kilojoules per mole. To estimate the total foam internal temperature, one must know the heat released when forming amino methyl formate, urea methyl formate, urea, and biuret (polyurea), in kilojoules per mole, and the reaction rate (reaction time).



This also explains why the density calculated from the foam index drastically differs from the theoretical and actual values for foams without fillers at 50 densities. The lower the density, the more closely the theoretical and actual values of foam density match.

The reaction of PU foam is based on two main chemical components: polyether polyols and isocyanates, along with other additives including water, dichlorodifluoromethane, foam stabilizers, and catalysts. These materials are instantly and vigorously mixed, reacting to form foam, a process that generates a considerable amount of heat.



Foam plastic is a porous material with a large surface area. While the heat generated at the edges of the foam can dissipate, the heat in the central part, due to the insulation effect of the foam, is more difficult to remove. In a typical reaction, the heat released raises the temperature of the center of the foam block to achieve curing. It has been observed that within 2 to 6 hours after foaming, temperatures can rise to 140-160°C, and sometimes even higher, around 180°C. If the temperature continues to rise, it can lead to core burning, smoking, and even spontaneous combustion.



Additionally, prolonged exposure of polyurethane foam to sunlight can trigger an auto-oxidation reaction, causing polymer degradation, discoloration, embrittlement, and a decrease in physical properties, rendering it unusable. Since the industrialization of polyurethane, core burning and aging have been hot topics of research and concern in the polyurethane industry.



Antioxidants are crucial additives in polyurethane foam production. Proper antioxidants prevent the decomposition of polyols, reduce the formation of by-products, decrease the risk of core burning, and can delay thermal oxidative aging during product use, thereby extending its lifespan. Commonly used antioxidants for PU foam are typically liquid and fall into three categories: aromatic amines (such as 5057), hindered phenols (such as 1135), and phosphite esters (such as PDP). For applications with low color requirements, a combination of aromatic amines and hindered phenols is generally used, while applications with higher color requirements may use a combination of hindered phenols and phosphite esters.



Furthermore, if products are frequently exposed to sunlight, a certain amount of UV stabilizers should be added to improve lifespan and resistance to yellowing. UV stabilizers mainly consist of UV absorbers and hindered amine light stabilizers (HALS). UV absorbers, such as benzotriazoles, benzophenones, and triazines, absorb harmful UV radiation and convert it into heat through intramolecular hydrogen bond transfer or cis-trans isomerization. HALS refers to amines with two methyl groups on each α-carbon atom, which, after photooxidation, transform into nitroso radicals. These radicals are considered stable components that can capture free radicals, regenerate nitroso radicals by reacting with peroxide radicals. UV blocking agents include carbon black, zinc oxide, titanium dioxide, and other pigments, which are used as colorants. These agents utilize their high dispersibility and covering power to reflect harmful UV radiation, protecting the polymer.